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• W2506087907 abstract "Abstract The synthesis of metal alloys usually requires harsh reaction conditions. We report herein that the chemical reactions of HAuCl 4 and cubic Cu 2 O nanocrystal in an ethanol‐water mixture solution at ambient temperature can form supported Au‐Cu alloys. The parallel galvanic replacement reaction between HAuCl 4 and Cu 2 O and disproportionation reaction of Cu 2 O simultaneously form Au and Cu atoms, respectively, on the Cu 2 O surface that cluster and grow into Au‐Cu alloys. The supported AuCu alloy particles exhibit excellent activity in catalyzing the liquid phase aerobic oxidation reaction of benzyl alcohol. These results demonstrate a novel approach to fabricate metal alloys with very mild conditions via oxide‐surface‐directed chemical synthesis." @default.
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• W2506087907 date "2016-08-02" @default.
• W2506087907 modified "2023-10-18" @default.
• W2506087907 title "Au-Cu Alloy Formation on Cubic Cu₂O Nanocrystals at Ambient Temperature and Their Catalytic Performance" @default.
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• W2506087907 doi "https://doi.org/10.1002/cnma.201600211" @default.
• W2506087907 hasPublicationYear "2016" @default.
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