FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2506987273> ?p ?o ?g. }

• W2506987273 endingPage "6245" @default.
• W2506987273 startingPage "6236" @default.
• W2506987273 abstract "A Ni-foam-structured PdNi nanoalloy catalyst engineered from nano- to macro-scales has been successfully fabricated for the catalytic deoxygenation of coalbed methane (CBM). The catalyst was obtainable by embedment of Pd nanoparticles onto Ni-foam substrate via a galvanic exchange reaction method and subsequent in situ activation in the reaction, which was active at low temperature, selective (no CO formation), and oscillation free in this CH4-rich catalytic combustion process. Special Pd@NiO (Pd nanoparticles partially wrapped by tiny NiO fragments) ensembles were formed in the galvanic deposition stage and could merely be transformed into PdNi nanoalloys in the real reaction stream at elevated temperatures (e.g., 450 °C or higher). Density functional theory (DFT) calculations were carried out to reveal the role of Ni decoration at Pd in PdNi nanoalloy catalyst for the CBM deoxygenation. By nature, the Pd–Ni alloying modified the electronic structure of surface Pd and led to a decrease in the O adsorption energy, which can be taken as the activity descriptor for the CBM deoxygenation. A reaction kinetic study indicated that the Ni decoration at Pd by Pd–Ni alloying lowered the apparent activation energy in comparison to the pristine Pd catalyst, while leading to an increase of the reaction order of O2 from −0.6 at Pd catalyst to −0.3. The foam-structured PdNi nanoalloy catalyst thus offered enhanced low-temperature activity and the elimination of oscillating phenomena as the result of a transient balance obtained between the cycles of O2 adsorption/activation and CH4 oxidation." @default.
• W2506987273 created "2016-08-23" @default.
• W2506987273 creator A5015595119 @default.
• W2506987273 creator A5017515691 @default.
• W2506987273 creator A5018742393 @default.
• W2506987273 creator A5021317456 @default.
• W2506987273 creator A5022170808 @default.
• W2506987273 creator A5071556628 @default.
• W2506987273 creator A5073136275 @default.
• W2506987273 creator A5084735564 @default.
• W2506987273 creator A5085852346 @default.
• W2506987273 date "2016-08-19" @default.
• W2506987273 modified "2023-10-16" @default.
• W2506987273 title "High-Performance PdNi Nanoalloy Catalyst in Situ Structured on Ni Foam for Catalytic Deoxygenation of Coalbed Methane: Experimental and DFT Studies" @default.
• W2506987273 cites W1513095955 @default.
• W2506987273 cites W1542807521 @default.
• W2506987273 cites W1622229158 @default.
• W2506987273 cites W1677594905 @default.
• W2506987273 cites W1970127494 @default.
• W2506987273 cites W1975114417 @default.
• W2506987273 cites W1978885192 @default.
• W2506987273 cites W1979613835 @default.
• W2506987273 cites W1980495221 @default.
• W2506987273 cites W1988595712 @default.
• W2506987273 cites W1989452871 @default.
• W2506987273 cites W1990285018 @default.
• W2506987273 cites W1996671263 @default.
• W2506987273 cites W1998825237 @default.
• W2506987273 cites W2001158776 @default.
• W2506987273 cites W2001889835 @default.
• W2506987273 cites W2003460517 @default.
• W2506987273 cites W2007395042 @default.
• W2506987273 cites W2018381210 @default.
• W2506987273 cites W2020918126 @default.
• W2506987273 cites W2022949418 @default.
• W2506987273 cites W2027713965 @default.
• W2506987273 cites W2028701907 @default.
• W2506987273 cites W2029579485 @default.
• W2506987273 cites W2036567988 @default.
• W2506987273 cites W2037030054 @default.
• W2506987273 cites W2037034031 @default.
• W2506987273 cites W2040236983 @default.
• W2506987273 cites W2046594089 @default.
• W2506987273 cites W2047165001 @default.
• W2506987273 cites W2048462006 @default.
• W2506987273 cites W2050421963 @default.
• W2506987273 cites W2068596706 @default.
• W2506987273 cites W2071816889 @default.
• W2506987273 cites W2072589903 @default.
• W2506987273 cites W2072715281 @default.
• W2506987273 cites W2079471947 @default.
• W2506987273 cites W2084222083 @default.
• W2506987273 cites W2087698390 @default.
• W2506987273 cites W2092901484 @default.
• W2506987273 cites W2093407501 @default.
• W2506987273 cites W2093448157 @default.
• W2506987273 cites W2093629088 @default.
• W2506987273 cites W2094769591 @default.
• W2506987273 cites W2103365704 @default.
• W2506987273 cites W2111899932 @default.
• W2506987273 cites W2133623857 @default.
• W2506987273 cites W2155521255 @default.
• W2506987273 cites W2190159336 @default.
• W2506987273 cites W2289160783 @default.
• W2506987273 cites W2320482012 @default.
• W2506987273 cites W2329664200 @default.
• W2506987273 cites W2419618737 @default.
• W2506987273 cites W2501547118 @default.
• W2506987273 cites W2949623356 @default.
• W2506987273 cites W49509540 @default.
• W2506987273 cites W2008342883 @default.
• W2506987273 cites W2012043623 @default.
• W2506987273 doi "https://doi.org/10.1021/acscatal.6b01226" @default.
• W2506987273 hasPublicationYear "2016" @default.
• W2506987273 type Work @default.
• W2506987273 sameAs 2506987273 @default.
• W2506987273 citedByCount "35" @default.
• W2506987273 countsByYear W25069872732017 @default.
• W2506987273 countsByYear W25069872732018 @default.
• W2506987273 countsByYear W25069872732019 @default.
• W2506987273 countsByYear W25069872732020 @default.
• W2506987273 countsByYear W25069872732021 @default.
• W2506987273 countsByYear W25069872732022 @default.
• W2506987273 countsByYear W25069872732023 @default.
• W2506987273 crossrefType "journal-article" @default.
• W2506987273 hasAuthorship W2506987273A5015595119 @default.
• W2506987273 hasAuthorship W2506987273A5017515691 @default.
• W2506987273 hasAuthorship W2506987273A5018742393 @default.
• W2506987273 hasAuthorship W2506987273A5021317456 @default.
• W2506987273 hasAuthorship W2506987273A5022170808 @default.
• W2506987273 hasAuthorship W2506987273A5071556628 @default.
• W2506987273 hasAuthorship W2506987273A5073136275 @default.
• W2506987273 hasAuthorship W2506987273A5084735564 @default.
• W2506987273 hasAuthorship W2506987273A5085852346 @default.
• W2506987273 hasConcept C127413603 @default.
• W2506987273 hasConcept C147789679 @default.
• W2506987273 hasConcept C150394285 @default.
• W2506987273 hasConcept C155672457 @default.

• next