FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2507122023> ?p ?o ?g. }

• W2507122023 endingPage "3747" @default.
• W2507122023 startingPage "3739" @default.
• W2507122023 abstract "Monocationic bis(hydrocarbyl)yttrium complexes [YR2(THF)2][A] (R = CH2SiMe3, CH2C6H4-o-NMe2; A = weakly coordinating anion) underwent hydrogenolysis using dihydrogen or phenylsilane to give a mixture of polynuclear solvent-stabilized dihydride cations [YH2(THF)2]n[A]n. The mixture composition as well as the nuclearity n depended on the starting material, solvent, and reaction conditions. NMR spectroscopic data in solution and X-ray diffraction data suggested that the main product was tetranuclear, although conclusive structural data were not obtained. DFT calculations supported a closo-type tetrahedral [YH2(THF)2]44+ core. The hydridic character of these cations was revealed by their reaction with benzophenone to give the bis(diphenylmethoxy) cation [Y(OCHPh2)2(THF)4][AlR4]. The reaction of this cluster with the (NNNN)-type macrocycle Me4TACD under dihydrogen gave the dinuclear tetrahydride dication with quadruply bridging hydride ligands, [Y2(μ-H)4(Me4TACD)2][A]2, analogous to the previously characterized lutetium derivative. NH-acidic (Me3TACD)H gave the dinuclear dihydride dication [Y2(μ-H)2(Me3TACD)2(THF)2][A]2." @default.
• W2507122023 created "2016-09-16" @default.
• W2507122023 creator A5002636361 @default.
• W2507122023 creator A5027523215 @default.
• W2507122023 creator A5029373017 @default.
• W2507122023 creator A5040122242 @default.
• W2507122023 creator A5045082437 @default.
• W2507122023 creator A5050757774 @default.
• W2507122023 creator A5070094610 @default.
• W2507122023 creator A5080202234 @default.
• W2507122023 creator A5086637541 @default.
• W2507122023 date "2015-07-17" @default.
• W2507122023 modified "2023-10-01" @default.
• W2507122023 title "Yttrium Dihydride Cation [YH₂(THF)₂]⁺_<i>n</i>: Aggregate Formation and Reaction with (NNNN)-Type Macrocycles" @default.
• W2507122023 cites W1560106512 @default.
• W2507122023 cites W1678991158 @default.
• W2507122023 cites W1963513960 @default.
• W2507122023 cites W1965100861 @default.
• W2507122023 cites W1966135886 @default.
• W2507122023 cites W1966959621 @default.
• W2507122023 cites W1968666687 @default.
• W2507122023 cites W1974752460 @default.
• W2507122023 cites W1977613306 @default.
• W2507122023 cites W1978721022 @default.
• W2507122023 cites W1981141489 @default.
• W2507122023 cites W1981898910 @default.
• W2507122023 cites W1982559099 @default.
• W2507122023 cites W1984112066 @default.
• W2507122023 cites W1990250276 @default.
• W2507122023 cites W1991364327 @default.
• W2507122023 cites W1995048699 @default.
• W2507122023 cites W1997652393 @default.
• W2507122023 cites W2005386158 @default.
• W2507122023 cites W2012157062 @default.
• W2507122023 cites W2018404012 @default.
• W2507122023 cites W2018849774 @default.
• W2507122023 cites W2026524732 @default.
• W2507122023 cites W2028235288 @default.
• W2507122023 cites W2039522937 @default.
• W2507122023 cites W2046950139 @default.
• W2507122023 cites W2055662875 @default.
• W2507122023 cites W2059008011 @default.
• W2507122023 cites W2064166918 @default.
• W2507122023 cites W2067619939 @default.
• W2507122023 cites W2071207881 @default.
• W2507122023 cites W2080883292 @default.
• W2507122023 cites W2087262575 @default.
• W2507122023 cites W2090519417 @default.
• W2507122023 cites W2092239667 @default.
• W2507122023 cites W2094304210 @default.
• W2507122023 cites W2095990585 @default.
• W2507122023 cites W2098123025 @default.
• W2507122023 cites W2103986047 @default.
• W2507122023 cites W2104942749 @default.
• W2507122023 cites W2116583059 @default.
• W2507122023 cites W2120413366 @default.
• W2507122023 cites W2150938994 @default.
• W2507122023 cites W2951597009 @default.
• W2507122023 cites W4243695726 @default.
• W2507122023 cites W4244226708 @default.
• W2507122023 doi "https://doi.org/10.1021/acs.organomet.5b00422" @default.
• W2507122023 hasPublicationYear "2015" @default.
• W2507122023 type Work @default.
• W2507122023 sameAs 2507122023 @default.
• W2507122023 citedByCount "17" @default.
• W2507122023 countsByYear W25071220232016 @default.
• W2507122023 countsByYear W25071220232017 @default.
• W2507122023 countsByYear W25071220232018 @default.
• W2507122023 countsByYear W25071220232019 @default.
• W2507122023 countsByYear W25071220232020 @default.
• W2507122023 countsByYear W25071220232021 @default.
• W2507122023 countsByYear W25071220232022 @default.
• W2507122023 countsByYear W25071220232023 @default.
• W2507122023 crossrefType "journal-article" @default.
• W2507122023 hasAuthorship W2507122023A5002636361 @default.
• W2507122023 hasAuthorship W2507122023A5027523215 @default.
• W2507122023 hasAuthorship W2507122023A5029373017 @default.
• W2507122023 hasAuthorship W2507122023A5040122242 @default.
• W2507122023 hasAuthorship W2507122023A5045082437 @default.
• W2507122023 hasAuthorship W2507122023A5050757774 @default.
• W2507122023 hasAuthorship W2507122023A5070094610 @default.
• W2507122023 hasAuthorship W2507122023A5080202234 @default.
• W2507122023 hasAuthorship W2507122023A5086637541 @default.
• W2507122023 hasConcept C106159729 @default.
• W2507122023 hasConcept C111771559 @default.
• W2507122023 hasConcept C145148216 @default.
• W2507122023 hasConcept C155647269 @default.
• W2507122023 hasConcept C161790260 @default.
• W2507122023 hasConcept C162324750 @default.
• W2507122023 hasConcept C178790620 @default.
• W2507122023 hasConcept C179104552 @default.
• W2507122023 hasConcept C181458950 @default.
• W2507122023 hasConcept C181886296 @default.
• W2507122023 hasConcept C185592680 @default.
• W2507122023 hasConcept C2776701986 @default.
• W2507122023 hasConcept C2777961443 @default.
• W2507122023 hasConcept C2778279444 @default.
• W2507122023 hasConcept C2779851234 @default.

• next