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- W2507407341 startingPage "13845" @default.
- W2507407341 abstract "Abstract The formation of actinide–transition metal heterobimetallics mediated by a terminal actinide imido complex was comprehensively studied. The reaction of the thorium imido complex [(η 5 ‐C 5 Me 5 ) 2 Th=N(mesityl)(DMAP)] ( 3 ), prepared from [(η 5 ‐C 5 Me 5 ) 2 ThMe 2 ] ( 1 ) and mesitylNH 2 or [(η 5 ‐C 5 Me 5 ) 2 Th(NHmesityl) 2 ] ( 2 ) in the presence of 4‐(dimethylamino)pyridine (DMAP), with copper(I) halides gave the first thorium–copper heterobimetallic compounds [(η 5 ‐C 5 Me 5 ) 2 Th(X){N(mesityl)Cu(DMAP)}] (X=Cl ( 4 ), Br ( 5 ), I ( 6 )). Complexes 4 – 6 feature an unusual geometry with a short Th−Cu distance, which DFT studies attribute to a weak donor–acceptor bond from the Cu + atom to the electropositive Th 4+ atom. They are reactive species, as was shown by their reaction with the dimethyl complex [(η 5 ‐C 5 Me 5 ) 2 ThMe 2 ] ( 1 ). Furthermore, a comparison between Th and early transition metals confirmed that Th 4+ exhibits distinctively different reactivity from d‐transition metals." @default.
- W2507407341 created "2016-09-16" @default.
- W2507407341 creator A5010213141 @default.
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- W2507407341 creator A5080638402 @default.
- W2507407341 creator A5080658249 @default.
- W2507407341 creator A5082812665 @default.
- W2507407341 date "2016-08-18" @default.
- W2507407341 modified "2023-10-16" @default.
- W2507407341 title "Experimental and Computational Studies on the Formation of Thorium-Copper Heterobimetallics" @default.
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