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- W2507500813 abstract "Poly(dichlorophosphazene) is a versatile precursor material for accessing new polymeric materials via the introduction of various side groups by chlorine replacement reactions. Herein, methods are described for the synthesis of a new series of phosphazene single- and mixed-substituent high polymers containing cyclic aliphatic rings, −CnH2n–1 (where n = 4–8). These reactions were preceded by model reactions using small molecule cyclic trimeric phosphazenes. The new high polymers are amorphous, transparent, and film- and membrane-forming materials with a wide range of glass transition temperatures (−60 to +40 °C) depending on the side groups and cosubstituents. All are hydrophobic and resistant to hydrolytic breakdown." @default.
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- W2507500813 date "2015-06-17" @default.
- W2507500813 modified "2023-10-14" @default.
- W2507500813 title "Phosphazene High Polymers and Models with Cyclic Aliphatic Side Groups: New Structure–Property Relationships" @default.
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- W2507500813 doi "https://doi.org/10.1021/acs.macromol.5b00946" @default.
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