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• W2507540406 endingPage "1010" @default.
• W2507540406 startingPage "967" @default.
• W2507540406 abstract "Organoboron and organosilicon compounds are widely used in chemical synthesis, and development of efficient, broadly applicable, and selective catalytic protocols that lead to their formation is of considerable interest. Similarly, a variety of catalytic methods for enantioselective formation of C-Si bonds have been disclosed that range from transformations that might be classified as cross-couplings, silyl hydride additions, carbonyl, imine, or allenyl additions to olefin metathesis processes, conjugate additions, and allylic substitutions. A notable recent development is that Lewis basic entities that are without a metal center can also serve as catalysts that promote site- and/or enan-tioselective generation of C-B and C-Si bonds. In 2008, as part of a program aimed at the design of efficient catalysts that promote enantioselective conjugate boron additions to α,β-unsaturated carbonyl substrates, we considered the possibility of catalytic cycles that are enabled by Lewis base activation of a B-B bond." @default.
• W2507540406 created "2016-09-16" @default.
• W2507540406 creator A5002537075 @default.
• W2507540406 creator A5003328029 @default.
• W2507540406 creator A5041910137 @default.
• W2507540406 creator A5054514619 @default.
• W2507540406 creator A5061022125 @default.
• W2507540406 creator A5081485832 @default.
• W2507540406 date "2016-07-25" @default.
• W2507540406 modified "2023-10-07" @default.
• W2507540406 title "Activation of <scp>B</scp> – <scp>B</scp> and <scp>B</scp> – <scp>Si</scp> Bonds and Synthesis of Organoboron and Organosilicon Compounds through Lewis Base‐Catalyzed Transformations ( <scp>n</scp> ?→? <scp>n</scp> ^* )" @default.
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