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• W2507595185 abstract "Use of a tandem ring-opening–ring-closing metathesis (RORCM) strategy for the synthesis of functional metathesis catalysts is reported. Ring opening of 7-substituted norbornenes and subsequent ring-closing metathesis forming a thermodynamically stable 6-membered ring lead to a very efficient synthesis of new catalysts from commercially available Grubbs’ catalysts. Hydroxy functionalized Grubbs’ first- as well as third-generation catalysts have been synthesized. Mechanistic studies have been performed to elucidate the order of attack of the olefinic bonds. This strategy was also used to synthesize the ruthenium methylidene complex." @default.
• W2507595185 created "2016-09-16" @default.
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• W2507595185 date "2016-09-05" @default.
• W2507595185 modified "2023-10-14" @default.
• W2507595185 title "Tandem Ring-Opening-Ring-Closing Metathesis for Functional Metathesis Catalysts" @default.
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• W2507595185 doi "https://doi.org/10.1002/anie.201604112" @default.
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