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- W2507728693 abstract "MnP has been subject of considerable attention due to its wealth of magnetic phases and complex magnetic transitions in the presence of a magnetic field and at high pressure. In the present polycrystalline Mn0·98Fe0·02P1-xAsx (with x = 0, 0.05 and 0.1) compounds, prepared by mechanical milling, a slight Fe doping lowers the Curie temperature TC from 291 K for MnP to 270 K and the TC is increased remarkably to 295 K through further replacing P by a small amount of As. In accordance with the ferromagnetic-paramagnetic transition, magnetocaloric effect (MCE) without thermal hysteresis is observed over a wide temperature range around room temperature. The maximum value of the magnetic-entropy change is 2.4 J/kg K for Mn0·98Fe0·02P0·9As0.1 at 300 K for a field change from 0 to 5 T. In addition, around the transition temperature of the ferromagnetic phase to screw phase, an external field can induce a first-order magnetic transition from the screw state to fan state and, for Mn0·98Fe0·02P, an inverse MCE with a maximal magnetic-entropy change ΔSm = 0.67 J/kg K for a field change of 3 T at 92 K has been found." @default.
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- W2507728693 date "2017-01-01" @default.
- W2507728693 modified "2023-09-26" @default.
- W2507728693 title "Magnetic and magnetocaloric properties of Mn0·98Fe0·02P1-xAsx compounds" @default.
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- W2507728693 doi "https://doi.org/10.1016/j.jallcom.2016.08.190" @default.
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