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• W2507778007 abstract "Acetonitrile (CH3 CN) is the simplest and one of the most stable nitriles. Reactions usually occur on the C≡N triple bond, while the C-H bond is very inert and can only be activated by a very strong base or a metal catalyst. It is demonstrated that C-H bonds can be activated by the cyano group under high pressure, but at room temperature. The hydrogen atom transfers from the CH3 to CN along the CH⋅⋅⋅N hydrogen bond, which produces an amino group and initiates polymerization to form a dimer, 1D chain, and 2D nanoribbon with mixed sp(2) and sp(3) bonded carbon. Finally, it transforms into a graphitic polymer by eliminating ammonia. This study shows that applying pressure can induce a distinctive reaction which is guided by the structure of the molecular crystal. It highlights the fact that very inert C-H can be activated by high pressure, even at room temperature and without a catalyst." @default.
• W2507778007 created "2016-09-16" @default.
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• W2507778007 date "2016-08-25" @default.
• W2507778007 modified "2023-10-01" @default.
• W2507778007 title "Polymerization of Acetonitrile via a Hydrogen Transfer Reaction from CH₃ to CN under Extreme Conditions" @default.
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• W2507778007 doi "https://doi.org/10.1002/anie.201606198" @default.
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