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- W2508092079 abstract "Abstract Four stereoisomers of whisky lactone were selectively synthesized in over 99% enantiomeric excess using an amino acid derivative as a resolving agent. Cbz‐L‐proline was the most effective resolving agent, and both trans ‐ and cis ‐stereoisomers were comparatively easily separated. Odour characteristics of whisky thionolactone were different among four stereomeric isomers, and only (3 S ,4 R )‐whisky thionolactone had mushroom and cis ‐jasmone like note. Among all isomers, only (3 R ,4 S )‐whisky lactone showed antibacterial activities against Staphylococcus aureus . Whisky thionolactone had higher activities than whisky lactone, and (3 R ,4 S )‐whisky thionolactone showed the strongest activities of all tested samples. Copyright © 2016 John Wiley & Sons, Ltd." @default.
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- W2508092079 date "2016-09-04" @default.
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- W2508092079 title "Synthesis, odour characteristics and antibacterial activities of the stereoisomeric forms of whisky lactone and its thiono analogues" @default.
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- W2508092079 doi "https://doi.org/10.1002/ffj.3341" @default.
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