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- W2508519794 abstract "Nickel-catalyzed cross-coupling reactions are experiencing a dramatic resurgence in recent years given their ability to employ a wider range of electrophiles as well as promote stereospecific or stereoselective transformations. In contrast to the extensively studied Pd catalysts that generally employ diamagnetic intermediates, Ni systems can more easily access various oxidation states including odd-electron configurations. For example, organometallic NiIII intermediates with aryl and/or alkyl ligands are commonly proposed as the active intermediates in cross-coupling reactions. Herein, we report the first isolated NiIII-dialkyl complex and show that this species is involved in stoichiometric and catalytic C-C bond formation reactions. Interestingly, the rate of C-C bond formation from a NiIII center is enhanced in the presence of an oxidant, suggesting the involvement of transient NiIV species. Indeed, such a NiIV species was observed and characterized spectroscopically for a nickelacycle system. Overall, these studies suggest that both NiIII and NiIV species could play an important role in a range of Ni-catalyzed cross-coupling reactions, especially those involving alkyl substrates." @default.
- W2508519794 created "2016-09-16" @default.
- W2508519794 creator A5021486550 @default.
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- W2508519794 creator A5063092113 @default.
- W2508519794 date "2016-09-21" @default.
- W2508519794 modified "2023-10-13" @default.
- W2508519794 title "Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon–Carbon Bond Formation Reactions" @default.
- W2508519794 cites W1561311795 @default.
- W2508519794 cites W1598759915 @default.
- W2508519794 cites W1600287229 @default.
- W2508519794 cites W1963881574 @default.
- W2508519794 cites W1963926801 @default.
- W2508519794 cites W1971455258 @default.
- W2508519794 cites W1977129830 @default.
- W2508519794 cites W1978851116 @default.
- W2508519794 cites W1981706397 @default.
- W2508519794 cites W1981997364 @default.
- W2508519794 cites W1989292538 @default.
- W2508519794 cites W1991992325 @default.
- W2508519794 cites W2000461729 @default.
- W2508519794 cites W2005108579 @default.
- W2508519794 cites W2007440128 @default.
- W2508519794 cites W2010599950 @default.
- W2508519794 cites W2013450477 @default.
- W2508519794 cites W2019326862 @default.
- W2508519794 cites W2034223040 @default.
- W2508519794 cites W2038330686 @default.
- W2508519794 cites W2041063003 @default.
- W2508519794 cites W2045114619 @default.
- W2508519794 cites W2045628767 @default.
- W2508519794 cites W2047864105 @default.
- W2508519794 cites W2049445412 @default.
- W2508519794 cites W2050836875 @default.
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- W2508519794 cites W2058692022 @default.
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- W2508519794 cites W2066344408 @default.
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- W2508519794 cites W2071129190 @default.
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- W2508519794 cites W2077703071 @default.
- W2508519794 cites W2079581485 @default.
- W2508519794 cites W2083792909 @default.
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- W2508519794 cites W2317071785 @default.
- W2508519794 cites W2318018747 @default.
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- W2508519794 cites W2325211194 @default.
- W2508519794 cites W2326037131 @default.
- W2508519794 cites W2327227881 @default.
- W2508519794 cites W2327472265 @default.
- W2508519794 cites W2327951570 @default.
- W2508519794 cites W2328190216 @default.
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- W2508519794 cites W2336805901 @default.
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- W2508519794 doi "https://doi.org/10.1021/jacs.6b06862" @default.
- W2508519794 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27599205" @default.
- W2508519794 hasPublicationYear "2016" @default.
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