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- W2508584524 abstract "Immobilization of silver nanoparticles (Ag NPs) to improve monodispersity and recyclability is crucial for applications in nanocatalysts. Herein, a novel protocol for stabilizer-free, effective, and in situ synthesis of Ag NPs on sulfhydryl-functionalized poly(glycidyl methacrylate) microspheres (PGMA-SH) was proposed. Ag NPs of 16.97 ± 3.15 nm were successfully grown on PGMA-SH, and remained monodisperse and stable even after sonication, washing, and long-term storage. Moreover, the Ag NPs on PGMA-SH (Ag NPs@PGMA-SH) composite exhibited excellent catalytic activity with an average normalized activity parameter of 4.38 × 10–3 L·mg–1·s–1 toward the reduction of 4-nitrophenol, which was 1.3–132 times higher than reported in literature. The composite can be easily recycled and showed excellent reusability as a conversion higher than 92% was achieved after 10 cycles. Thus, the preparation of Ag NPs@PGMA-SH has been proven a feasible, straightforward, and effective protocol, which would facilitate the applications of Ag NPs in environmental control." @default.
- W2508584524 created "2016-09-16" @default.
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- W2508584524 creator A5063605100 @default.
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- W2508584524 date "2015-06-19" @default.
- W2508584524 modified "2023-09-28" @default.
- W2508584524 title "In Situ Synthesis of Monodisperse Silver Nanoparticles on Sulfhydryl-Functionalized Poly(glycidyl methacrylate) Microspheres for Catalytic Reduction of 4-Nitrophenol" @default.
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- W2508584524 doi "https://doi.org/10.1021/acs.iecr.5b01010" @default.
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