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- W2509035035 endingPage "4245" @default.
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- W2509035035 abstract "Herein, the use of a well-defined low-valent cobalt(I) catalyst [HCo(PMe3)4] capable of performing the highly regio- and stereoselective hydrosilylation of internal alkynes is reported. The reaction can be applied to a variety of hydrosilanes, symmetrical and unsymmetrical alkynes, giving in many cases a single hydrosilylation isomer. Experimental and theoretical studies suggest the key step to be a hydro-cobaltation and that the reaction proceeds through a classical Chalk-Harrod mechanism." @default.
- W2509035035 created "2016-09-16" @default.
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- W2509035035 date "2016-08-23" @default.
- W2509035035 modified "2023-10-17" @default.
- W2509035035 title "Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst" @default.
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- W2509035035 doi "https://doi.org/10.1021/acs.orglett.6b01987" @default.
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