Matches in SemOpenAlex for { <https://semopenalex.org/work/W2509133729> ?p ?o ?g. }
- W2509133729 endingPage "3997" @default.
- W2509133729 startingPage "3988" @default.
- W2509133729 abstract "A series of diiron complexes of N,C,S-tridentate ligands containing a 6-, 5-, or 4-amino-2-pyridyl group, [{Fe(μ-L-κ3N,C,S)(CO)2}Fe(CO)3] (2, L = o-apyBPT; 3, L = m-apyBPT; 4, L = p-apyBPT), was synthesized: apyBPT is a doubly deprotonated form of 3′-(amino-2″-pyridyl)-1,1′-biphenyl-2-thiol. Complexes 2–4 were converted to the mononuclear iron(II) complexes trans-[Fe(L-κ3N,C,S)(CO)(PMe2Ph)2] (6, L = o-apyBPT; 7, L = m-apyBPT; 8, L = p-apyBPT). In 2 and 6, the o-amino group is close to Fe bound to the aminopyridyl group. Cyclic voltammograms of 2–4 exhibit two consecutive one-electron reduction events, and catalytic current for proton reduction appears in the presence of acetic acid. The reduction potentials of 2–4 are similar to each other, while the overpotential for proton reduction with o-amino complex 2 is ca. 0.2 V lower than those with 3 and 4. In the mononuclear complexes 6–8, the redox potentials for the FeIII/FeII couple are dependent on the position of the amino group in the pyridine ring, which..." @default.
- W2509133729 created "2016-09-16" @default.
- W2509133729 creator A5034484632 @default.
- W2509133729 creator A5060588315 @default.
- W2509133729 creator A5072070755 @default.
- W2509133729 date "2015-08-06" @default.
- W2509133729 modified "2023-09-24" @default.
- W2509133729 title "Di- and Mononuclear Iron Complexes of N,C,S-Tridentate Ligands Containing an Aminopyridyl Group: Effect of the Pendant Amine Site on Catalytic Properties for Proton Reduction" @default.
- W2509133729 cites W1963666284 @default.
- W2509133729 cites W1966242744 @default.
- W2509133729 cites W1969635440 @default.
- W2509133729 cites W1971396352 @default.
- W2509133729 cites W1972014272 @default.
- W2509133729 cites W1972125087 @default.
- W2509133729 cites W1976291766 @default.
- W2509133729 cites W1991426583 @default.
- W2509133729 cites W1991745854 @default.
- W2509133729 cites W2004242300 @default.
- W2509133729 cites W2004837355 @default.
- W2509133729 cites W2009212916 @default.
- W2509133729 cites W2011910038 @default.
- W2509133729 cites W2013046539 @default.
- W2509133729 cites W2015782805 @default.
- W2509133729 cites W2019486533 @default.
- W2509133729 cites W2021444944 @default.
- W2509133729 cites W2022630904 @default.
- W2509133729 cites W2023029157 @default.
- W2509133729 cites W2026598559 @default.
- W2509133729 cites W2028361335 @default.
- W2509133729 cites W2028465433 @default.
- W2509133729 cites W2033852744 @default.
- W2509133729 cites W2034377056 @default.
- W2509133729 cites W2036809572 @default.
- W2509133729 cites W2041864511 @default.
- W2509133729 cites W2042626435 @default.
- W2509133729 cites W2046545090 @default.
- W2509133729 cites W2051004100 @default.
- W2509133729 cites W2053434133 @default.
- W2509133729 cites W2060869358 @default.
- W2509133729 cites W2061679831 @default.
- W2509133729 cites W2062220773 @default.
- W2509133729 cites W2063334178 @default.
- W2509133729 cites W2065818181 @default.
- W2509133729 cites W2068453999 @default.
- W2509133729 cites W2068796168 @default.
- W2509133729 cites W2070127123 @default.
- W2509133729 cites W2072348323 @default.
- W2509133729 cites W2072760145 @default.
- W2509133729 cites W2077979133 @default.
- W2509133729 cites W2078807614 @default.
- W2509133729 cites W2082986749 @default.
- W2509133729 cites W2091258026 @default.
- W2509133729 cites W2102464022 @default.
- W2509133729 cites W2104796556 @default.
- W2509133729 cites W2131350133 @default.
- W2509133729 cites W2138881932 @default.
- W2509133729 cites W2148896972 @default.
- W2509133729 cites W2312629688 @default.
- W2509133729 cites W2313172416 @default.
- W2509133729 cites W2319898429 @default.
- W2509133729 cites W2320639994 @default.
- W2509133729 cites W2324777999 @default.
- W2509133729 cites W2326959021 @default.
- W2509133729 cites W2328034507 @default.
- W2509133729 cites W2333385365 @default.
- W2509133729 cites W2333794926 @default.
- W2509133729 cites W2950627929 @default.
- W2509133729 cites W2951181528 @default.
- W2509133729 cites W4211159207 @default.
- W2509133729 doi "https://doi.org/10.1021/acs.organomet.5b00366" @default.
- W2509133729 hasPublicationYear "2015" @default.
- W2509133729 type Work @default.
- W2509133729 sameAs 2509133729 @default.
- W2509133729 citedByCount "14" @default.
- W2509133729 countsByYear W25091337292016 @default.
- W2509133729 countsByYear W25091337292017 @default.
- W2509133729 countsByYear W25091337292018 @default.
- W2509133729 countsByYear W25091337292019 @default.
- W2509133729 countsByYear W25091337292020 @default.
- W2509133729 countsByYear W25091337292021 @default.
- W2509133729 countsByYear W25091337292022 @default.
- W2509133729 countsByYear W25091337292023 @default.
- W2509133729 crossrefType "journal-article" @default.
- W2509133729 hasAuthorship W2509133729A5034484632 @default.
- W2509133729 hasAuthorship W2509133729A5060588315 @default.
- W2509133729 hasAuthorship W2509133729A5072070755 @default.
- W2509133729 hasConcept C111335779 @default.
- W2509133729 hasConcept C121332964 @default.
- W2509133729 hasConcept C131779359 @default.
- W2509133729 hasConcept C155647269 @default.
- W2509133729 hasConcept C161790260 @default.
- W2509133729 hasConcept C178790620 @default.
- W2509133729 hasConcept C185592680 @default.
- W2509133729 hasConcept C188027245 @default.
- W2509133729 hasConcept C2524010 @default.
- W2509133729 hasConcept C2781311116 @default.
- W2509133729 hasConcept C33923547 @default.
- W2509133729 hasConcept C54516573 @default.