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- W2509179979 abstract "A non-isolated pentagon rule metallic carbide clusterfullerene containing a heptagonal ring, Sc2C2@Cs(hept)-C88, was isolated from the raw soot obtained by electric arc vaporization of graphite rods packed with Sc2O3 and graphite powder under a helium atmosphere. The Sc2C2@Cs(hept)-C88 was purified by multistage high-performance liquid chromatography (HPLC), cocrystallized with Ni-(octaethylporphyrin), and characterized by single-crystal X-ray diffraction. The diffraction data revealed a zigzag Sc2C2 unit inside an unprecedented Cs(hept)-C88 carbon cage containing 13 pentagons, 32 hexagons, and 1 heptagon. Calculations suggest that the observed nonclassical fullerene could be a kinetically trapped species derived from the recently reported Sc2C2@C2v(9)-C86 via a direct C2 insertion." @default.
- W2509179979 created "2016-09-16" @default.
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- W2509179979 date "2016-09-21" @default.
- W2509179979 modified "2023-10-16" @default.
- W2509179979 title "Zigzag Sc<sub>2</sub>C<sub>2</sub> Carbide Cluster inside a [88]Fullerene Cage with One Heptagon, Sc<sub>2</sub>C<sub>2</sub>@<i>C</i><sub><i>s</i></sub>(hept)-C<sub>88</sub>: A Kinetically Trapped Fullerene Formed by C<sub>2</sub> Insertion?" @default.
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- W2509179979 doi "https://doi.org/10.1021/jacs.6b07912" @default.
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