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• W2509366327 startingPage "2564" @default.
• W2509366327 abstract "Benzimidazole-branched bi-anchoring organic dyes that contained triphenylamine/phenothiazine donors, 2-cyanoacrylic acid acceptors, and various π linkers were synthesized and examined as sensitizers for dye-sensitized solar cells. The structure-activity relationships in these dyes were systematically investigated by using absorption spectroscopy, cyclic voltammetry, and density functional theory calculations. The wavelength of the absorption peak was more-heavily influenced by the nature of the π linker than by the nature of the donor. For a given donor, the absorption maximum (λmax ) was red-shifted on changing the π linker from phenyl to 2,2'-bithiophene, whilst the dyes that contained triphenylamine units displayed higher molar extinction coefficients (ϵ) than their analogous phenothiazine-based triphenylamine dyes, which led to good light-harvesting properties in the triphenylamine-based dyes. Electrochemical data for the dyes indicated that the triphenylamine-based dyes possessed relatively low-lying HOMOs, which could be beneficial for suppressing back electron transfer from the conduction band of TiO2 to the oxidized dyes, owing to facile regeneration of the oxidized dye by the electrolyte. The best performance in the DSSCs was observed for a dye that possessed a triphenylamine donor and 2,2'-bithiophene π linkers. Electron impedance spectroscopy (EIS) studies revealed that the use of triphenylamine as the donor and phenyl or 2,2'-bithiophene as the π linkers was beneficial for disrupting the dark current and charge-recombination kinetics, which led to a long electron lifetime of the injected electrons in the conduction band of TiO2 ." @default.
• W2509366327 created "2016-09-16" @default.
• W2509366327 creator A5014425893 @default.
• W2509366327 creator A5030027887 @default.
• W2509366327 creator A5041216956 @default.
• W2509366327 creator A5061513451 @default.
• W2509366327 date "2016-09-05" @default.
• W2509366327 modified "2023-10-17" @default.
• W2509366327 title "Bi-anchoring Organic Dyes that Contain Benzimidazole Branches for Dye-Sensitized Solar Cells: Effects of π Spacer and Peripheral Donor Groups" @default.
• W2509366327 cites W1502462133 @default.
• W2509366327 cites W1921792941 @default.
• W2509366327 cites W1965904224 @default.
• W2509366327 cites W1966065400 @default.
• W2509366327 cites W1966826151 @default.
• W2509366327 cites W1967641444 @default.
• W2509366327 cites W1968059051 @default.
• W2509366327 cites W1968268204 @default.
• W2509366327 cites W1969260515 @default.
• W2509366327 cites W1971459108 @default.
• W2509366327 cites W1972960386 @default.
• W2509366327 cites W1973039514 @default.
• W2509366327 cites W1973126916 @default.
• W2509366327 cites W1974315985 @default.
• W2509366327 cites W1975624378 @default.
• W2509366327 cites W1978890358 @default.
• W2509366327 cites W1980216394 @default.
• W2509366327 cites W1981451973 @default.
• W2509366327 cites W1982356449 @default.
• W2509366327 cites W1983158217 @default.
• W2509366327 cites W1983410334 @default.
• W2509366327 cites W1983592349 @default.
• W2509366327 cites W1984576643 @default.
• W2509366327 cites W1984880144 @default.
• W2509366327 cites W1986683953 @default.
• W2509366327 cites W1989370834 @default.
• W2509366327 cites W1990189209 @default.
• W2509366327 cites W1990604768 @default.
• W2509366327 cites W1991980035 @default.
• W2509366327 cites W1993804258 @default.
• W2509366327 cites W1994403294 @default.
• W2509366327 cites W1995692147 @default.
• W2509366327 cites W1995966981 @default.
• W2509366327 cites W1996166165 @default.
• W2509366327 cites W1996889612 @default.
• W2509366327 cites W1998065542 @default.
• W2509366327 cites W2002545855 @default.
• W2509366327 cites W2004014816 @default.
• W2509366327 cites W2006681399 @default.
• W2509366327 cites W2007339862 @default.
• W2509366327 cites W2010152465 @default.
• W2509366327 cites W2010805194 @default.
• W2509366327 cites W2014124406 @default.
• W2509366327 cites W2016411991 @default.
• W2509366327 cites W2016422110 @default.
• W2509366327 cites W2017987607 @default.
• W2509366327 cites W2019442630 @default.
• W2509366327 cites W2019771911 @default.
• W2509366327 cites W2019834122 @default.
• W2509366327 cites W2021552106 @default.
• W2509366327 cites W2023037074 @default.
• W2509366327 cites W2023158145 @default.
• W2509366327 cites W2023271753 @default.
• W2509366327 cites W2024122111 @default.
• W2509366327 cites W2030211033 @default.
• W2509366327 cites W2030213238 @default.
• W2509366327 cites W2030372083 @default.
• W2509366327 cites W2031207229 @default.
• W2509366327 cites W2031393714 @default.
• W2509366327 cites W2031500963 @default.
• W2509366327 cites W2031540147 @default.
• W2509366327 cites W2034261084 @default.
• W2509366327 cites W2034600111 @default.
• W2509366327 cites W2035773736 @default.
• W2509366327 cites W2036132526 @default.
• W2509366327 cites W2036144247 @default.
• W2509366327 cites W2041264795 @default.
• W2509366327 cites W2042647439 @default.
• W2509366327 cites W2045464764 @default.
• W2509366327 cites W2045867203 @default.
• W2509366327 cites W2048093472 @default.
• W2509366327 cites W2051900605 @default.
• W2509366327 cites W2052491795 @default.
• W2509366327 cites W2053680794 @default.
• W2509366327 cites W2053782439 @default.
• W2509366327 cites W2054737507 @default.
• W2509366327 cites W2054763302 @default.
• W2509366327 cites W2055069556 @default.
• W2509366327 cites W2055177367 @default.
• W2509366327 cites W2058943636 @default.
• W2509366327 cites W2058985078 @default.
• W2509366327 cites W2060485154 @default.
• W2509366327 cites W2061343703 @default.
• W2509366327 cites W2062304476 @default.
• W2509366327 cites W2063664926 @default.
• W2509366327 cites W2063711078 @default.
• W2509366327 cites W2064937078 @default.
• W2509366327 cites W2065958683 @default.
• W2509366327 cites W2067071393 @default.

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