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- W2509459968 abstract "Bile acid anions are biosurfactants which form small micelles. To enhance the hydrophobic volume of the micelle, bile salts are used as mixed micelles with non-ionic surfactants. Micellar-bound bile acids (sodium-hyodeoxycholate, HD and sodium-cholate, C in binary mixed micelles with non-ionic surfactant Triton X-100) at concentration of 10 cmc have higher pKa values than bile acids from the aqueous solution. Different pKa values of micellar and non-micellar bile acids (ΔpKa) are due to the excess Gibbs energy GHAE which is a function of interaction coefficient and mole fraction of Triton X-100 in the binary surfactant mixture. In the mixed micelles ΔpKa values show synergistic interactions between different building units, similarly as interaction coefficient." @default.
- W2509459968 created "2016-09-16" @default.
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- W2509459968 date "2016-12-01" @default.
- W2509459968 modified "2023-09-29" @default.
- W2509459968 title "Binary mixed micelles of triton X-100 and selected bile salts: Thermodynamic stabilization and pKa values of micellar bile acids" @default.
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- W2509459968 doi "https://doi.org/10.1016/j.jct.2016.08.030" @default.
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