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- W2509963287 abstract "The Marangoni effect describes fluid flow near an interface in response to a surface tension gradient. Here, we demonstrate that the Marangoni effect is the underlying mechanism for flow driven feature formation in an azobenzene-containing polymer film; features formed in azobenzene-containing polymers are often referred to as surface relief gratings or SRGs. An amorphous poly(4-(acryloyloxyhexyloxy)-4′-pentylazobenzene) was synthesized and studied as a model polymer. To isolate the surface tension driven flow from the surface tension pattern inscription step, the surface tension gradient was preprogrammed via photoisomerization of azobenzene in a glassy polymer film without forming topographical features. Subsequently, the latent image was developed in the absence of light by annealing above the glass transition temperature where the polymer is a liquid. The polymer flow direction was controlled with precision by inducing different surface tension changes in the exposed regions, in accordance with expect..." @default.
- W2509963287 created "2016-09-16" @default.
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- W2509963287 date "2016-09-02" @default.
- W2509963287 modified "2023-09-24" @default.
- W2509963287 title "Marangoni Instability Driven Surface Relief Grating in an Azobenzene-Containing Polymer Film" @default.
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- W2509963287 doi "https://doi.org/10.1021/acs.macromol.6b01848" @default.
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