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- W2510029401 abstract "The Fe 2p photoelectron lines, as measured by X-ray photoelectron spectra (XPS), of a series of tris(β-diketonato)iron(III) complexes, are sensitive to the electron donating and withdrawing properties of the ligand attached to the iron atom. The maximum binding energy of the Fe 2p3/2 envelope revealed a linear relationship with the combined Gordy scale group electronegativity of the R-groups substituted on the respective β-diketonato ligand (RCOCHCOR′)−. A linear relationship between the binding energies and other electronic parameters was also obtained. Within these relationships, there are specific clusters of complexes defined by the amount of CF3 groups substituted per β-diketonato ligand. These specific clusters of complexes show an opposite trend inversely proportional to the general trend. It was also shown that the Fe 2p photoelectron peaks can be fitted with calculated multiplet splitting peaks, according to the synthetically generated multiplet splitting test spectra, as calculated by Gupta and Sen for a free Fe(III) ion. The tris(β-diketonato)iron(III) complexes containing unsymmetrically substituted β-diketonato ligands (RCOCHCOR′)−, were fitted with two different sets of multiplet splitting peaks, which are assigned to the fac and mer isomers of these complexes." @default.
- W2510029401 created "2016-09-16" @default.
- W2510029401 creator A5000341829 @default.
- W2510029401 creator A5048547840 @default.
- W2510029401 date "2016-11-01" @default.
- W2510029401 modified "2023-10-18" @default.
- W2510029401 title "XPS Fe 2p peaks from iron tris(β-diketonates): Electronic effect of the β-diketonato ligand" @default.
- W2510029401 cites W1612862975 @default.
- W2510029401 cites W1870475543 @default.
- W2510029401 cites W1951206760 @default.
- W2510029401 cites W1965589309 @default.
- W2510029401 cites W1966512504 @default.
- W2510029401 cites W1967040140 @default.
- W2510029401 cites W1970000657 @default.
- W2510029401 cites W1973417213 @default.
- W2510029401 cites W1976052880 @default.
- W2510029401 cites W1982248954 @default.
- W2510029401 cites W1982698915 @default.
- W2510029401 cites W1982905459 @default.
- W2510029401 cites W1986537956 @default.
- W2510029401 cites W1987859727 @default.
- W2510029401 cites W1988490681 @default.
- W2510029401 cites W1989203801 @default.
- W2510029401 cites W1990935272 @default.
- W2510029401 cites W1995616559 @default.
- W2510029401 cites W1998115907 @default.
- W2510029401 cites W1998300739 @default.
- W2510029401 cites W1998483039 @default.
- W2510029401 cites W1998959641 @default.
- W2510029401 cites W2000760372 @default.
- W2510029401 cites W2003962650 @default.
- W2510029401 cites W2006806329 @default.
- W2510029401 cites W2007283649 @default.
- W2510029401 cites W2007984172 @default.
- W2510029401 cites W2008482924 @default.
- W2510029401 cites W2010718514 @default.
- W2510029401 cites W2011089736 @default.
- W2510029401 cites W2015009425 @default.
- W2510029401 cites W2016170590 @default.
- W2510029401 cites W2016882452 @default.
- W2510029401 cites W2018884484 @default.
- W2510029401 cites W2020593170 @default.
- W2510029401 cites W2021176812 @default.
- W2510029401 cites W2022228162 @default.
- W2510029401 cites W2023207400 @default.
- W2510029401 cites W2023271753 @default.
- W2510029401 cites W2029065336 @default.
- W2510029401 cites W2036176009 @default.
- W2510029401 cites W2037270587 @default.
- W2510029401 cites W2038531158 @default.
- W2510029401 cites W2039869820 @default.
- W2510029401 cites W2041502149 @default.
- W2510029401 cites W2041535772 @default.
- W2510029401 cites W2044563645 @default.
- W2510029401 cites W2046919975 @default.
- W2510029401 cites W2051673554 @default.
- W2510029401 cites W2055652960 @default.
- W2510029401 cites W2057606714 @default.
- W2510029401 cites W2061849609 @default.
- W2510029401 cites W2063586325 @default.
- W2510029401 cites W2066008387 @default.
- W2510029401 cites W2066689831 @default.
- W2510029401 cites W2069272247 @default.
- W2510029401 cites W2070488219 @default.
- W2510029401 cites W2075758407 @default.
- W2510029401 cites W2078353661 @default.
- W2510029401 cites W2081722500 @default.
- W2510029401 cites W2083446348 @default.
- W2510029401 cites W2094040786 @default.
- W2510029401 cites W2098547240 @default.
- W2510029401 cites W2104284828 @default.
- W2510029401 cites W2109292342 @default.
- W2510029401 cites W2143981217 @default.
- W2510029401 cites W2148284063 @default.
- W2510029401 cites W2150345533 @default.
- W2510029401 cites W2150951305 @default.
- W2510029401 cites W2159461275 @default.
- W2510029401 cites W2160790360 @default.
- W2510029401 cites W2166771548 @default.
- W2510029401 cites W2197387411 @default.
- W2510029401 cites W2319459624 @default.
- W2510029401 cites W2319538555 @default.
- W2510029401 cites W2320527194 @default.
- W2510029401 cites W2419032333 @default.
- W2510029401 cites W2439462566 @default.
- W2510029401 cites W2509954293 @default.
- W2510029401 cites W2950406848 @default.
- W2510029401 cites W4244356752 @default.
- W2510029401 cites W2176228092 @default.
- W2510029401 doi "https://doi.org/10.1016/j.poly.2016.08.042" @default.
- W2510029401 hasPublicationYear "2016" @default.
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