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• W2510114089 abstract "Palladium-catalyzed cross-coupling reactions have revolutionized organic synthesis on both benchtop and industrial scales. Recent advances in such chemistry can be attributed in part to the development of appropriately constructed ancillary ligands that enable new and/or challenging substrate transformations to be achieved with greater selectivity and/or under increasingly mild conditions. In this chapter we provide a focused examination of phosphine ancillary ligand design, specifically in the context of challenging and sought-after palladium-catalyzed C(sp 2)-E bond formation (E = NH2, OH, and F) where monoarylation selectivity and/or product-forming C-E reductive elimination may be limiting factors. The featured examples serve to highlight the utility of “repurposing” phosphine ligands developed in the context of mechanistically unrelated catalytic applications, and to illustrate the potential complications that can arise in “rational” ancillary ligand design when the ancillary ligand itself is transformed by the substrate in the course of palladium-catalyzed cross-coupling chemistry." @default.
• W2510114089 created "2016-09-16" @default.
• W2510114089 creator A5020096924 @default.
• W2510114089 creator A5062660227 @default.
• W2510114089 date "2016-09-02" @default.
• W2510114089 modified "2023-10-07" @default.
• W2510114089 title "Application of Sterically Demanding Phosphine Ligands in Palladium‐Catalyzed Cross‐Coupling leading to C( <i>sp</i> ² )─E Bond Formation (E = <scp> NH ₂ </scp> , <scp>OH</scp> , and F)" @default.
• W2510114089 cites W1972661867 @default.
• W2510114089 cites W1975279514 @default.
• W2510114089 cites W1984839013 @default.
• W2510114089 cites W1987086188 @default.
• W2510114089 cites W1992996188 @default.
• W2510114089 cites W1993847723 @default.
• W2510114089 cites W1996878551 @default.
• W2510114089 cites W1999619622 @default.
• W2510114089 cites W2001920359 @default.
• W2510114089 cites W2006683822 @default.
• W2510114089 cites W2013760130 @default.
• W2510114089 cites W2017146152 @default.
• W2510114089 cites W2018310119 @default.
• W2510114089 cites W2020417568 @default.
• W2510114089 cites W2023100599 @default.
• W2510114089 cites W2025358565 @default.
• W2510114089 cites W2025729516 @default.
• W2510114089 cites W2026756252 @default.
• W2510114089 cites W2031774809 @default.
• W2510114089 cites W2042653815 @default.
• W2510114089 cites W2044426249 @default.
• W2510114089 cites W2047340213 @default.
• W2510114089 cites W2054459983 @default.
• W2510114089 cites W2065001227 @default.
• W2510114089 cites W2066024831 @default.
• W2510114089 cites W2069756819 @default.
• W2510114089 cites W2070160936 @default.
• W2510114089 cites W2074720955 @default.
• W2510114089 cites W2077742962 @default.
• W2510114089 cites W2080925478 @default.
• W2510114089 cites W2083790594 @default.
• W2510114089 cites W2084301636 @default.
• W2510114089 cites W2086602016 @default.
• W2510114089 cites W2087272850 @default.
• W2510114089 cites W2088943620 @default.
• W2510114089 cites W2093800950 @default.
• W2510114089 cites W2094065729 @default.
• W2510114089 cites W2097225154 @default.
• W2510114089 cites W2097981039 @default.
• W2510114089 cites W2100440614 @default.
• W2510114089 cites W2101826827 @default.
• W2510114089 cites W2104699219 @default.
• W2510114089 cites W2110478240 @default.
• W2510114089 cites W2111118274 @default.
• W2510114089 cites W2115474120 @default.
• W2510114089 cites W2116242606 @default.
• W2510114089 cites W2116919923 @default.
• W2510114089 cites W2123321938 @default.
• W2510114089 cites W2123605549 @default.
• W2510114089 cites W2124006483 @default.
• W2510114089 cites W2126541092 @default.
• W2510114089 cites W2138288808 @default.
• W2510114089 cites W2139003771 @default.
• W2510114089 cites W2144635871 @default.
• W2510114089 cites W2145120220 @default.
• W2510114089 cites W2147062409 @default.
• W2510114089 cites W2149315142 @default.
• W2510114089 cites W2151090182 @default.
• W2510114089 cites W2155577396 @default.
• W2510114089 cites W2157594577 @default.
• W2510114089 cites W2159541026 @default.
• W2510114089 cites W2165352032 @default.
• W2510114089 cites W2168866252 @default.
• W2510114089 cites W2169269629 @default.
• W2510114089 cites W2170544497 @default.
• W2510114089 cites W2172024079 @default.
• W2510114089 cites W2174845629 @default.
• W2510114089 cites W2183259185 @default.
• W2510114089 cites W2227778904 @default.
• W2510114089 cites W2261683138 @default.
• W2510114089 cites W2317645396 @default.
• W2510114089 cites W2321669473 @default.
• W2510114089 cites W2325495180 @default.
• W2510114089 cites W2326600284 @default.
• W2510114089 cites W2332293511 @default.
• W2510114089 cites W2333129245 @default.
• W2510114089 cites W2348951409 @default.
• W2510114089 cites W2553947721 @default.
• W2510114089 cites W2736864779 @default.
• W2510114089 cites W2949167459 @default.
• W2510114089 cites W2950971696 @default.
• W2510114089 cites W4238575790 @default.
• W2510114089 cites W4253902331 @default.
• W2510114089 cites W4292903356 @default.
• W2510114089 cites W4295067868 @default.
• W2510114089 cites W4362234547 @default.
• W2510114089 cites W639160051 @default.
• W2510114089 doi "https://doi.org/10.1002/9781118839621.ch5" @default.
• W2510114089 hasPublicationYear "2016" @default.
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