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- W251011875 startingPage "1046" @default.
- W251011875 abstract "The 3 $^{1}mathrm{ensuremath{Pi}}_{mathit{u}}$ensuremath{leftarrow}X $^{1}mathrm{ensuremath{Sigma}}_{mathit{g}}^{+}$ and 3 $^{1}mathrm{ensuremath{Sigma}}_{mathit{u}}^{+}$ensuremath{leftarrow}X $^{1}mathrm{ensuremath{Sigma}}_{mathit{g}}^{+}$ band systems of ${mathrm{K}}_{2}$ are studied by the polarization-labeling spectroscopy method. An observation of isotope shifts of rotationally resolved lines in both systems reveals that the previous vibrational numbering in the 3 $^{1}mathrm{ensuremath{Pi}}_{mathit{u}}$ and 3 $^{1}mathrm{ensuremath{Sigma}}_{mathit{u}}^{+}$ states is incorrect by 1 and 3 vibrational quanta, respectively. An analysis is carried out for both states. We present the resulting molecular parameters that describe the 3 $^{1}mathrm{ensuremath{Pi}}_{mathit{u}}$ state to 55% and the 3 $^{1}mathrm{ensuremath{Sigma}}_{mathit{u}}^{+}$ state to 71% of their potential well depths." @default.
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- W251011875 date "1995-02-01" @default.
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- W251011875 doi "https://doi.org/10.1103/physreva.51.1046" @default.
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