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• W2510185211 abstract "We report a new class of glycerol–water system to transform FGD gypsum into α-calcium sulfate hemihydrate (α-HH) mediated by trace NaCl and Na2EDTA to regulate the phase transformation rate as well as the crystal morphology to achieve crystals with high mechanical strength. NaCl plays a role in accelerating the nucleation and crystal growth process, whereas Na2EDTA regulates the morphology of α-HH from columnar to lamellar. The paste made from columnar α-HH with higher aspect ratio deserves higher dry bending/compressive strength of 13.6/37.6 MPa, which is comparable with those prepared in nitrate–water medium, chloride–water medium, or by autoclave method. This study provides an improved alternative of glycerol–water system to transform FGD gypsum into α-HH with controlled morphology, high mechanical strength, and less corrosion to the equipment. We also establish the relationship between the mechanical strength of paste and the aspect ratio of α-HH crystals." @default.
• W2510185211 created "2016-09-16" @default.
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• W2510185211 date "2016-08-18" @default.
• W2510185211 modified "2023-10-13" @default.
• W2510185211 title "Trace NaCl and Na₂EDTA Mediated Synthesis of α-Calcium Sulfate Hemihydrate in Glycerol–Water Solution" @default.
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• W2510185211 doi "https://doi.org/10.1021/acs.iecr.6b02064" @default.
• W2510185211 hasPublicationYear "2016" @default.
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