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- W2510188698 abstract "The electric double layer containing a negatively charged compact-layer surface was designed by modifying the 3-mercaptopropionic acid self-assembled monolayer (3-MPA SAM) on the Au electrode. Thus the surface potential of the compact layer on the SAM can be adjusted by shifting the dissociation equilibrium of the carboxyl group (-COOH). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to study the electrochemical reversibility of Fe(CN)63−/4− at the above mentioned electrode, respectively. A key finding is that the negatively charged 3-MPA SAM surface can depress the electrochemical reversibility of Fe(CN)63−/4−, while the formation of ion-pairs between the dissociated carboxylate groups (-COO−) and the divalent cations on the monolayer can improve the electrochemical reversibility of Fe(CN)63−/4− by increasing the surface potential of the compact layer. Further, the electrochemical reversibility of Fe(CN)63−/4− can also be regulated by a mixed solution of different divalent cations. The logarithm of ion-pair formation constants (log K) with the -COO− were determined to be 2.78 ± 0.03, 2.75 ± 0.04, 2.69 ± 0.04 for Ba2+, Ca2+, Mg2+ by electrochemical titration method, respectively." @default.
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- W2510188698 date "2016-01-01" @default.
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- W2510188698 title "Regulating the Electrochemical Reversibility of Fe(CN)<sub>6</sub><sup>3−/4−</sup> by Altering the Surface Potential of the Compact Layer" @default.
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