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- W2510262663 abstract "The effective utilization of industrially waste cinder for electroanalytical applications by trapping the hexacyanometallate (HCF) units from Fe 3 + , N1 2 + , Co 3 + , etc into the interlayer galleries of cinder has been reported. Prussian blue (PB) is an Fe(III)-HCF with mixed valence and zeolite type properties. In the present investigation, the intercalation property of Tl + with PB/cinder paste electrode (designated as PBCPE) has been utilized for the analytical purpose. Basic cyclic voltammetric experiments with Tl + in 0.1 M KNO 3 results in a continuous insertion of Tl + ions inside the PB gallery with the ejection of K + ions. The insertion rate of Tl + ions in the PBCPE was much faster as compared to that in traditional PB-modified electrodes. The PBCPE has also been utilized for sensitive determination of Tl + ions in real samples." @default.
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- W2510262663 date "2003-04-01" @default.
- W2510262663 modified "2023-09-27" @default.
- W2510262663 title "Voltammetric determination of thallium(I) on a prussian blue/cinder paste electrode" @default.
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