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- W2510582893 abstract "A base-metal, Fe(0)-catalyzed hydrosilylation of imines to obtain amines is reported here which outperforms its noble-metal congeners with the highest TON of 17000. The catalyst, (aNHC)Fe(CO)4, works under very mild conditions, with extremely low catalyst loading (down to 0.005 mol %), and exhibits excellent chemoselectivity. The facile nature of the imine reduction under mild conditions has been further demonstrated by reducing imines towards expensive commercial amines and biologically important N-alkylated sugars, which are difficult to achieve otherwise. A mechanistic pathway and the source of chemoselectivity for imine hydrosilylation have been proposed on the basis of the well-defined catalyst and isolable intermediates along the catalytic cycle." @default.
- W2510582893 created "2016-09-16" @default.
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- W2510582893 date "2016-08-24" @default.
- W2510582893 modified "2023-10-17" @default.
- W2510582893 title "A Highly Efficient Base-Metal Catalyst: Chemoselective Reduction of Imines to Amines Using An Abnormal-NHC–Fe(0) Complex" @default.
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- W2510582893 doi "https://doi.org/10.1021/acs.organomet.6b00478" @default.
- W2510582893 hasPublicationYear "2016" @default.
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