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- W2510632730 endingPage "3068" @default.
- W2510632730 startingPage "3060" @default.
- W2510632730 abstract "Computational studies (M06) have been performed in synergy with experimental studies to show that the thermodynamics for insertion of CO into an oxorhenium–hydride bond to form a formyl ligand is favorable despite conventional wisdom to the contrary. Further, it is shown that insertion of CO into formyl ligands to form α-dicarbonyl ligands is also a viable pathway and results in hydroxy carbonyl or formate complexes, depending on the nature of the ancillary ligand." @default.
- W2510632730 created "2016-09-16" @default.
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- W2510632730 date "2016-08-29" @default.
- W2510632730 modified "2023-09-24" @default.
- W2510632730 title "Mechanism for the Reaction of CO with Oxorhenium Hydrides: Migratory Insertion of CO into Rhenium Hydride and Formyl Bonds leads to Migration from Rhenium to the Oxo Ligand" @default.
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- W2510632730 doi "https://doi.org/10.1021/acs.organomet.6b00591" @default.
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