Matches in SemOpenAlex for { <https://semopenalex.org/work/W2510983604> ?p ?o ?g. }
- W2510983604 endingPage "14987" @default.
- W2510983604 startingPage "14979" @default.
- W2510983604 abstract "A new synthetic route to functionalized neutral and anionic azadiphospholes from easily accessible starting materials is described. Equimolar reaction of Na(OCP) and N-(2,6-dimethylphenyl)pivalimidoyl chloride 2 a cleanly affords the imidoxy-functionalized 1,2,4-azadiphosphole 3 a. Using Na(OCP) and imidoyl chloride in a 2:1 ratio leads to an anionic four-membered ring Na[4 a], which has been structurally characterized. During 16 h at room temperature, Na[4 a] rearranges to the anionic 1,3,4-azadiphospholide Na[5 a] with release of carbon monoxide. Applying the more sterically demanding N-(2,6-diisopropylphenyl)pivalimidoyl chloride allows isolation of the 1,3,4-azadiphospholide Na[5 b] in good yield (>70 %). Possible mechanisms leading to the new isomeric azadiphospholides have been investigated with the aid of high-level composite calculations." @default.
- W2510983604 created "2016-09-16" @default.
- W2510983604 creator A5025163552 @default.
- W2510983604 creator A5061621298 @default.
- W2510983604 creator A5063987926 @default.
- W2510983604 date "2016-08-31" @default.
- W2510983604 modified "2023-10-17" @default.
- W2510983604 title "A Convenient Synthesis of 1,2,4- and 1,3,4-Azadiphospholes" @default.
- W2510983604 cites W1596244585 @default.
- W2510983604 cites W1969849214 @default.
- W2510983604 cites W1971798161 @default.
- W2510983604 cites W1973803567 @default.
- W2510983604 cites W1979746302 @default.
- W2510983604 cites W1985188082 @default.
- W2510983604 cites W2002695691 @default.
- W2510983604 cites W2007288088 @default.
- W2510983604 cites W2011330047 @default.
- W2510983604 cites W2016799427 @default.
- W2510983604 cites W2022138307 @default.
- W2510983604 cites W2026377548 @default.
- W2510983604 cites W2029487589 @default.
- W2510983604 cites W2033432852 @default.
- W2510983604 cites W2033890502 @default.
- W2510983604 cites W2038064914 @default.
- W2510983604 cites W2043117282 @default.
- W2510983604 cites W2043160623 @default.
- W2510983604 cites W2043606901 @default.
- W2510983604 cites W2046773428 @default.
- W2510983604 cites W2052778674 @default.
- W2510983604 cites W2058555504 @default.
- W2510983604 cites W2060820894 @default.
- W2510983604 cites W2065720971 @default.
- W2510983604 cites W2070605504 @default.
- W2510983604 cites W2071234191 @default.
- W2510983604 cites W2074323583 @default.
- W2510983604 cites W2082148410 @default.
- W2510983604 cites W2086898377 @default.
- W2510983604 cites W2094837341 @default.
- W2510983604 cites W2095241286 @default.
- W2510983604 cites W2098633637 @default.
- W2510983604 cites W2106860992 @default.
- W2510983604 cites W2109309942 @default.
- W2510983604 cites W2110330134 @default.
- W2510983604 cites W2111631349 @default.
- W2510983604 cites W2119636833 @default.
- W2510983604 cites W2120945279 @default.
- W2510983604 cites W2121237359 @default.
- W2510983604 cites W2121619418 @default.
- W2510983604 cites W2130282285 @default.
- W2510983604 cites W2138185047 @default.
- W2510983604 cites W2138964030 @default.
- W2510983604 cites W2141274799 @default.
- W2510983604 cites W2145789127 @default.
- W2510983604 cites W2148028358 @default.
- W2510983604 cites W2154890653 @default.
- W2510983604 cites W2160923526 @default.
- W2510983604 cites W2167365820 @default.
- W2510983604 cites W2168935222 @default.
- W2510983604 cites W2170843307 @default.
- W2510983604 cites W2213178578 @default.
- W2510983604 cites W2228886655 @default.
- W2510983604 cites W2328790504 @default.
- W2510983604 cites W2950014048 @default.
- W2510983604 cites W2951062436 @default.
- W2510983604 cites W2951971321 @default.
- W2510983604 cites W4211202589 @default.
- W2510983604 cites W4234138851 @default.
- W2510983604 cites W4245769682 @default.
- W2510983604 cites W4249287564 @default.
- W2510983604 cites W4250432154 @default.
- W2510983604 cites W4252960040 @default.
- W2510983604 cites W4255262934 @default.
- W2510983604 cites W4367011154 @default.
- W2510983604 cites W65030645 @default.
- W2510983604 doi "https://doi.org/10.1002/chem.201602864" @default.
- W2510983604 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27576588" @default.
- W2510983604 hasPublicationYear "2016" @default.
- W2510983604 type Work @default.
- W2510983604 sameAs 2510983604 @default.
- W2510983604 citedByCount "31" @default.
- W2510983604 countsByYear W25109836042017 @default.
- W2510983604 countsByYear W25109836042018 @default.
- W2510983604 countsByYear W25109836042019 @default.
- W2510983604 countsByYear W25109836042020 @default.
- W2510983604 countsByYear W25109836042021 @default.
- W2510983604 countsByYear W25109836042022 @default.
- W2510983604 crossrefType "journal-article" @default.
- W2510983604 hasAuthorship W2510983604A5025163552 @default.
- W2510983604 hasAuthorship W2510983604A5061621298 @default.
- W2510983604 hasAuthorship W2510983604A5063987926 @default.
- W2510983604 hasConcept C134121241 @default.
- W2510983604 hasConcept C155647269 @default.
- W2510983604 hasConcept C161790260 @default.
- W2510983604 hasConcept C178790620 @default.
- W2510983604 hasConcept C179104552 @default.
- W2510983604 hasConcept C185592680 @default.
- W2510983604 hasConcept C191897082 @default.
- W2510983604 hasConcept C192562407 @default.