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• W2511053977 endingPage "4778" @default.
• W2511053977 startingPage "4768" @default.
• W2511053977 abstract "The regio- and stereoselective cyclopolymerization of a series of 1,6-heptadiynes and 1,7-octadiynes, i.e., of 4,4-bis(ethoxycarbonyl)-1,7-heptadiyne (M1), 4-ethoxycarbonyl-4-(1R,2S,5R)-(−)-menthyloxycarbonyl-1,6-heptadiyne (M2), (R,S)-4,5-bis((1R,2S,5R)-(−)-menthyloxymethylcarboxymethyl)-1,7-octadiyne (M3), and (S,S/R,R)-4,5-bis((1R,2S,5R)-(−)-menthyloxymethylcarboxymethyl)-1,7-octadiyne (M4), by the action of the molybdenum–imidoalkylidene N-heterocyclic carbene (NHC) complexes (Mo(N-2,6-Me2C6H3)(CHCMe2Ph)(OTf)2(IMesH2) (I1), Mo(N-2,6-Me2C6H3)(CHCMe3)(OTf)2(IMesH2) (I2), (Mo(N-2,6-Me2-C6H3)(CHCMe2Ph)(OTf)(OCH(CF3)2)(IMesH2) (I3), Mo(N-2,6-Cl2C6H3)(CHCMe3)(OTf)2(IMes) (I4, IMesH2 = 1,3-dimesitylimidazolidin-2-ylidene, IMes = 1,3-dimesitylimidazolin-2-ylidene) and by the molybdenum–imidoalkylidene monoaryloxide monopyrrolide (MAP) complexes Mo(N-2,6-iPr2-C6H3)(CHCMe2Ph)(2,5-Me2-pyrrolide)(O-2,6-Me2-C6H3) (MAP1), Mo(N-2,6-iPr2-C6H3)(CHCMe2Ph)(2,5-Me2-pyrrolide)(O-2,6-Mes2-C6H3) (MAP2), and Mo(N-2-tBu-C6H4)(CHCMe2Ph)(2,5-Me2-pyrrolide)(O-2,6-Mes2-C6H3) (MAP3) is described. With initiators I1–I4, high regioselectivity >96% was observed in the polymerization of M1–M4, allowing for virtually selective α-insertion. These initiators displayed also high stereoselectivity, allowing for all-trans polyenes with up to 96% syndioselectivity. By contrast, the MAP initiators MAP1–MAP3 showed poor regioselectivity (26–62% α-selectivity). A polymerization mechanism is proposed that explains for the high stereo- and regioselectivity of the Mo–imidoalkylidene NHC complexes." @default.
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• W2511053977 date "2015-07-14" @default.
• W2511053977 modified "2023-09-27" @default.
• W2511053977 title "Mechanism of the Regio- and Stereoselective Cyclopolymerization of 1,6-Hepta- and 1,7-Octadiynes by High Oxidation State Molybdenum–Imidoalkylidene <i>N</i>-Heterocyclic Carbene Initiators" @default.
• W2511053977 cites W1666135105 @default.
• W2511053977 cites W1966421866 @default.
• W2511053977 cites W1967467556 @default.
• W2511053977 cites W1967824835 @default.
• W2511053977 cites W1970500371 @default.
• W2511053977 cites W1978910915 @default.
• W2511053977 cites W1979639505 @default.
• W2511053977 cites W1982062166 @default.
• W2511053977 cites W1982305813 @default.
• W2511053977 cites W1983650454 @default.
• W2511053977 cites W1983946729 @default.
• W2511053977 cites W1989387230 @default.
• W2511053977 cites W1989455944 @default.
• W2511053977 cites W1997576488 @default.
• W2511053977 cites W1997951194 @default.
• W2511053977 cites W2000108344 @default.
• W2511053977 cites W2003774452 @default.
• W2511053977 cites W2005546983 @default.
• W2511053977 cites W2007506520 @default.
• W2511053977 cites W2008554735 @default.
• W2511053977 cites W2009167658 @default.
• W2511053977 cites W2010302497 @default.
• W2511053977 cites W2010391847 @default.
• W2511053977 cites W2011584091 @default.
• W2511053977 cites W2011820483 @default.
• W2511053977 cites W2013812539 @default.
• W2511053977 cites W2014472323 @default.
• W2511053977 cites W2019310334 @default.
• W2511053977 cites W2020597134 @default.
• W2511053977 cites W2039125938 @default.
• W2511053977 cites W2048233559 @default.
• W2511053977 cites W2065168738 @default.
• W2511053977 cites W2065540263 @default.
• W2511053977 cites W2073050103 @default.
• W2511053977 cites W2074516052 @default.
• W2511053977 cites W2075523821 @default.
• W2511053977 cites W2075865247 @default.
• W2511053977 cites W2078790770 @default.
• W2511053977 cites W2078888214 @default.
• W2511053977 cites W2080577553 @default.
• W2511053977 cites W2086579182 @default.
• W2511053977 cites W2091832167 @default.
• W2511053977 cites W2093327302 @default.
• W2511053977 cites W2106390039 @default.
• W2511053977 cites W2107068294 @default.
• W2511053977 cites W2126686907 @default.
• W2511053977 cites W2141992921 @default.
• W2511053977 cites W2156549291 @default.
• W2511053977 cites W2165692837 @default.
• W2511053977 cites W2209766196 @default.
• W2511053977 cites W2313756843 @default.
• W2511053977 cites W2319095366 @default.
• W2511053977 cites W2324119026 @default.
• W2511053977 cites W2324901906 @default.
• W2511053977 cites W2325441008 @default.
• W2511053977 cites W2329701221 @default.
• W2511053977 cites W2332840076 @default.
• W2511053977 cites W2333298986 @default.
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• W2511053977 cites W2418809164 @default.
• W2511053977 cites W2478990149 @default.
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• W2511053977 doi "https://doi.org/10.1021/acs.macromol.5b01185" @default.
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