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- W2511285823 abstract "The reaction of sulfanylmethyllithiums generated from benzylsulfanes and n-BuLi with N,N-dimethylthioformamide followed by the addition of Grignard reagents gave 2-phenyl-2-sulfanyl tertiary amines in moderate to good yields. A range of Grignard reagents involving primary alkyl, aryl, vinyl, and alkynyl Grignard reagents were used. Two carbon-carbon bond-forming reactions were achieved through a one-pot reaction. The reaction showed good to high diastereoselectivity, particularly with alkynyl Grignard reagents." @default.
- W2511285823 created "2016-09-16" @default.
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- W2511285823 date "2016-08-30" @default.
- W2511285823 modified "2023-09-30" @default.
- W2511285823 title "Sequential Addition Reaction of Sulfanylmethyllithiums and Grignard Reagents to Thioformamides Leading to the Formation of 2-Phenyl-2-sulfanylethyl Tertiary Amines" @default.
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- W2511285823 doi "https://doi.org/10.1021/acs.joc.6b01857" @default.
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