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- W2511378518 abstract "Three new polyoxovanadate-based metal-organic polyhedra (VMOPs) have been successfully synthesized and structurally characterized. Single crystals of three VMOPs were obtained by reaction of VCl3 and different carboxylate ligands (2,5-H2TDA = thiophene-2,5-dicarboxylic acid for VMOP-4, m-H2BDC = 1,3-benzenedicarboxylic acid for VMOP-5, 2,6-H2NDC = 2,6-naphthalenedicarboxylic aid for VMOP-6) under solvothermal conditions. Though all of the three hybrids feature the same {V(V)V4(IV)} units, their structures exhibit differences changing from truncated triangular prism to truncated quadrangular prism to octahedron, mainly depending on the nature of carboxylate ligands. Furthermore, the magnetic investigations reveal that VMOP-4-6 show similar ferromagnetic behaviors." @default.
- W2511378518 created "2016-09-16" @default.
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- W2511378518 date "2016-08-12" @default.
- W2511378518 modified "2023-10-17" @default.
- W2511378518 title "Ligand-Directed Assembly of Polyoxovanadate-Based Metal–Organic Polyhedra" @default.
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- W2511378518 doi "https://doi.org/10.1021/acs.inorgchem.6b01338" @default.
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