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- W2511397570 abstract "A porous luminescent zinc(II) metal–organic framework (MOF) with a NbO net [Zn2(tptc)(apy)2–x(H2O)x]·H2O (1) (where x ≈ 1, apy = aminopyridine, H4tptc = terphenyl-3,3″,5,5″-tetracarboxylic acid), constructed using paddlewheel [Zn2(COO)4] clusters and π-electron-rich terphenyl-tetracarboxylic acid, has been solvothermally synthesized and characterized. Interestingly, the material displays efficient, reversible adsorption of radioactive I2 in vapor and in solution (up to 216 wt %). The strong affinity for I2 is mainly due to it having large porosity, a conjugated π-electron aromatic system, halogen bonds, and electron-donating aminos. Furthermore, luminescent study indicated that 1 exhibits high sensitivity to electron-deficient nitrobenzene explosives via fluorescence quenching." @default.
- W2511397570 created "2016-09-16" @default.
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- W2511397570 date "2016-08-31" @default.
- W2511397570 modified "2023-10-16" @default.
- W2511397570 title "A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection" @default.
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- W2511397570 doi "https://doi.org/10.1021/acs.inorgchem.6b01312" @default.
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