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- W2511444435 abstract "Lead-free Cu2+-modified (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCZT−xCu2+) piezoelectric ceramics was synthesized by sol-gel method. The effects of Cu2+ additions on sintering characteristics, the phase structure, microstructure, electrical properties and complex impedance characteristic were investigated systematically. The XRD patterns exhibited a pure perovskite structure without impurity phase in all samples. SEM micrographs, temperature dependence of dielectric constant and polarization-electric field (P-E) hysteresis loops indicated that a small amount of Cu2+ addition affected the properties obviously. The results revealed that the addition of Cu2+ significantly improved the sinterability of BCZT ceramics which resulted in a reduction of sintering temperature from 1440 °C to 1230 °C. The TG-DSC was analyzed to verify the reaction process of BCZT−Cu2+ materials. (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 ceramics with x=0.020 Cu2+ exhibited good electrical properties: εm=12,112, Tc=360 K, εr=2614, tan δ=0.026, Kp=0.47 and d33=382 pC/N. The results indicated that Cu2+-modified BCZT ceramics could be a promising candidate for commercial purposes." @default.
- W2511444435 created "2016-09-16" @default.
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- W2511444435 date "2016-12-01" @default.
- W2511444435 modified "2023-10-16" @default.
- W2511444435 title "Low temperature sintering and dielectric properties of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3−xCu2+ ceramics obtained by the sol-gel technique" @default.
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- W2511444435 doi "https://doi.org/10.1016/j.ceramint.2016.08.076" @default.
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