Matches in SemOpenAlex for { <https://semopenalex.org/work/W2511636087> ?p ?o ?g. }
- W2511636087 endingPage "3547" @default.
- W2511636087 startingPage "3542" @default.
- W2511636087 abstract "The development of non-precious-metal (NPM) catalysts to replace the Pt alloys currently used in fuel cells to facilitate the oxygen reduction reaction (ORR) is a vital step in the widespread utilization of fuel cells. Currently, the ORR mechanism for NPM catalysts is not well understood, prohibiting the design and preparation of improved NPM catalysts. We conducted a kinetic isotope effect (KIE) study to identify the rate-determining step (RDS) of this intricate electrocatalytic reaction involving multiple proton-coupled electron transfer (PCET) processes. We observed a KIE of about 2 for the ORR catalyzed by a NPM catalyst, which demonstrates that for these electrocatalysts protons are involved in the RDS during ORR. These results contribute to a more complete understanding of the ORR mechanism and suggest that the design of future NPM catalysts must include careful consideration of the role of protons during ORR." @default.
- W2511636087 created "2016-09-16" @default.
- W2511636087 creator A5004462230 @default.
- W2511636087 creator A5021345935 @default.
- W2511636087 creator A5077256370 @default.
- W2511636087 creator A5087335230 @default.
- W2511636087 date "2016-08-26" @default.
- W2511636087 modified "2023-10-14" @default.
- W2511636087 title "Elucidating Proton Involvement in the Rate-Determining Step for Pt/Pd-Based and Non-Precious-Metal Oxygen Reduction Reaction Catalysts Using the Kinetic Isotope Effect" @default.
- W2511636087 cites W1168565912 @default.
- W2511636087 cites W1483851170 @default.
- W2511636087 cites W1984698067 @default.
- W2511636087 cites W1985618996 @default.
- W2511636087 cites W1987916847 @default.
- W2511636087 cites W2001939047 @default.
- W2511636087 cites W2005930128 @default.
- W2511636087 cites W2019043925 @default.
- W2511636087 cites W2020007931 @default.
- W2511636087 cites W2027033107 @default.
- W2511636087 cites W2039714242 @default.
- W2511636087 cites W2042827028 @default.
- W2511636087 cites W2045673759 @default.
- W2511636087 cites W2049683745 @default.
- W2511636087 cites W2053537246 @default.
- W2511636087 cites W2058735547 @default.
- W2511636087 cites W2061726561 @default.
- W2511636087 cites W2072050656 @default.
- W2511636087 cites W2085020302 @default.
- W2511636087 cites W2088450247 @default.
- W2511636087 cites W2088640500 @default.
- W2511636087 cites W2090622507 @default.
- W2511636087 cites W2118244214 @default.
- W2511636087 cites W2120124901 @default.
- W2511636087 cites W2123816415 @default.
- W2511636087 cites W2136558288 @default.
- W2511636087 cites W2142244352 @default.
- W2511636087 cites W2152103620 @default.
- W2511636087 cites W2155421119 @default.
- W2511636087 cites W2157381553 @default.
- W2511636087 cites W2167035995 @default.
- W2511636087 cites W2232615295 @default.
- W2511636087 cites W2314505024 @default.
- W2511636087 cites W2321381449 @default.
- W2511636087 cites W2329247413 @default.
- W2511636087 cites W2329760721 @default.
- W2511636087 cites W2332052133 @default.
- W2511636087 cites W2345547682 @default.
- W2511636087 cites W2410039023 @default.
- W2511636087 cites W2472624251 @default.
- W2511636087 cites W2507574566 @default.
- W2511636087 cites W3023208512 @default.
- W2511636087 cites W4239343206 @default.
- W2511636087 cites W4378639049 @default.
- W2511636087 doi "https://doi.org/10.1021/acs.jpclett.6b01235" @default.
- W2511636087 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27550191" @default.
- W2511636087 hasPublicationYear "2016" @default.
- W2511636087 type Work @default.
- W2511636087 sameAs 2511636087 @default.
- W2511636087 citedByCount "49" @default.
- W2511636087 countsByYear W25116360872017 @default.
- W2511636087 countsByYear W25116360872018 @default.
- W2511636087 countsByYear W25116360872019 @default.
- W2511636087 countsByYear W25116360872020 @default.
- W2511636087 countsByYear W25116360872021 @default.
- W2511636087 countsByYear W25116360872022 @default.
- W2511636087 countsByYear W25116360872023 @default.
- W2511636087 crossrefType "journal-article" @default.
- W2511636087 hasAuthorship W2511636087A5004462230 @default.
- W2511636087 hasAuthorship W2511636087A5021345935 @default.
- W2511636087 hasAuthorship W2511636087A5077256370 @default.
- W2511636087 hasAuthorship W2511636087A5087335230 @default.
- W2511636087 hasConcept C110010208 @default.
- W2511636087 hasConcept C121332964 @default.
- W2511636087 hasConcept C123669783 @default.
- W2511636087 hasConcept C127413603 @default.
- W2511636087 hasConcept C135889238 @default.
- W2511636087 hasConcept C147789679 @default.
- W2511636087 hasConcept C161790260 @default.
- W2511636087 hasConcept C17525397 @default.
- W2511636087 hasConcept C178790620 @default.
- W2511636087 hasConcept C179104552 @default.
- W2511636087 hasConcept C185592680 @default.
- W2511636087 hasConcept C21951064 @default.
- W2511636087 hasConcept C2987658370 @default.
- W2511636087 hasConcept C2994571290 @default.
- W2511636087 hasConcept C42360764 @default.
- W2511636087 hasConcept C518104683 @default.
- W2511636087 hasConcept C52859227 @default.
- W2511636087 hasConcept C544153396 @default.
- W2511636087 hasConcept C54516573 @default.
- W2511636087 hasConcept C58364064 @default.
- W2511636087 hasConcept C62520636 @default.
- W2511636087 hasConcept C65024703 @default.
- W2511636087 hasConcept C69928629 @default.
- W2511636087 hasConcept C75473681 @default.
- W2511636087 hasConceptScore W2511636087C110010208 @default.
- W2511636087 hasConceptScore W2511636087C121332964 @default.
- W2511636087 hasConceptScore W2511636087C123669783 @default.