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- W2511650416 abstract "An efficient 2-oxo-group-promoted direct coupling reaction between 2-oxo aldehydes and hydroperoxides has been developed. The method has been used successfully for the generation of different 2-oxo esters and acids. This reaction harnesses the hydrogen-bonding-induced self-decomposition tendency of hydroperoxides; the intermediates produced by this process then attack the aldehyde or iminium ion to generate cross-coupled products either by direct coupling or by an amine-catalysed pathway. No external oxidants or metal catalysts are required for our method, and the reaction takes place at room temperature." @default.
- W2511650416 created "2016-09-16" @default.
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- W2511650416 date "2016-10-05" @default.
- W2511650416 modified "2023-10-07" @default.
- W2511650416 title "2-Oxo-Driven Coupling Reactions of 2-Oxo Aldehydes/2-Oxo Iminium Ions and Hydroperoxides at Room Temperature" @default.
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- W2511650416 doi "https://doi.org/10.1002/ejoc.201600795" @default.
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