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- W2511653868 abstract "Under the thermal treatment of films cast from mixed solutions, the immobilization of cobalt complexes of tetraphenylporphyrin and phthalocyanin disulfonate on the thermally structured poly(acrylonitrile) was studied in the temperature interval of 180-250°C. At the initial stages, the interaction of metalloporphyrin with HCN produced by the degradation of PAN is assumed to take place; then, the reaction product containing thermoreactive -CH=N- groups participates in the thermal structuring of PAN. The thermally structured PAN containing immobilized cobalt tetraporphyrin is characterized by an improved thermal resistance in air and inert medium. Under carbonization of thermally structured PAN containing 5% of immobilized cobalt tetraporphyrin, the yield of carbon residue increases by 25%." @default.
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- W2511653868 date "2000-01-01" @default.
- W2511653868 modified "2023-10-07" @default.
- W2511653868 title "IMMOBILIZATION OF PORPHYRIN METALLOCOMPLEXES ON THERMALLY STRUCTURED POLY(ACRYLONITRILE)" @default.
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