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- W2511697210 abstract "Abstract For the first time, conventional and controlled miniemulsion polymerization of vinyl acetate (VAc) was performed using gamma radiation as alternative source of initiation. Reversible addition-fragmentation chain transfer/macromolecular design via interchange of xanthates (RAFT/MADIX) technique was applied to control the polymerization process. For this purpose, S-2-cyano-2-propyl-O-ethyl xanthate ( C TA) was used as chain transfer agent. To illustrate the advantages of using gamma radiation instead of other initiation sources, we compared gamma radiation and the 2,2′-azobis(isobutyronitrile) (AIBN) as initiators in the polymerization mediated by RAFT/MADIX technique. Compared with conventional miniemulsion polymerization, the controlled polymerization process allowed obtaining monomodal molecular weight distribution s and a significant control over the molecular weight distribution. The miniemulsions showed colloidal stability during polymerization and stable latices were obtained in a short reaction time with high conversion. Gamma radiation demonstrated to be a better initiator than AIBN for the miniemulsion polymerization of VAc, mediated by RAFT/MADIX." @default.
- W2511697210 created "2016-09-16" @default.
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- W2511697210 date "2016-10-01" @default.
- W2511697210 modified "2023-10-03" @default.
- W2511697210 title "Synthesis of narrow molecular weight distribution polyvinyl acetate by gamma–rays initiated RAFT/MADIX miniemulsion polymerization" @default.
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- W2511697210 doi "https://doi.org/10.1016/j.polymer.2016.09.004" @default.
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