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• W2511711514 endingPage "205" @default.
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• W2511711514 abstract "Abstract The densities, ρ, speeds of sound, u, and molar heat capacities, CP, of 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (i) + 1-butyl-3-methylimidazolium tetrafluoroborate (j); 1-butyl-3-methylimidazolium tetrafluoroborate (i) + 1-ethyl-3-methylimidazolium tetrafluoroborate (j) and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (i) + 1-ethyl-3-methylimidazolium tetrafluoroborate (j) mixtures at temperatures (293.15, 298.15, 303.15, 308.15) K and excess molar enthalpies, HE, for the same mixtures at temperature (298.15) K have been measured over entire range of mole fraction under atmospheric pressure. Using experimental data, excess molar volumes, VE, excess isentropic compressiblities, κ S E , excess molar enthalpies, HE and excess molar heat capacities, C P E have been determined. The VE, κ S E , HE and C P E data have been fitted to Redlich-Kister equation to estimate the binary adjustable parameters and standard deviations between experimental and calculated values. The topology of the constituent molecules (Graph theory) has been utilized to predict VE, κ S E , HE and C P E data of the studied mixtures. The comparison of VE, κ S E , HE and C P E values determined by Graph theory with their corresponding experimental values lends additional support to the proposed molecular entities existing in mixtures along with various processes involved in the (i + j) mixtures formation. Further, IR studies and quantum mechanical calculations support the presence of proposed molecular entities in the studied mixtures." @default.
• W2511711514 created "2016-09-16" @default.
• W2511711514 creator A5021060141 @default.
• W2511711514 creator A5051969354 @default.
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• W2511711514 creator A5087831780 @default.
• W2511711514 date "2016-12-01" @default.
• W2511711514 modified "2023-10-03" @default.
• W2511711514 title "Topological investigations of molecular interactions in binary ionic liquid mixtures with a common ion: Excess molar volumes, excess isentropic compressibilities, excess molar enthalpies and excess molar heat capacities" @default.
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• W2511711514 doi "https://doi.org/10.1016/j.jct.2016.08.010" @default.
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