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- W2511755013 abstract "Abstract Die thermische Reaktion des zweiatomigen Tantalnitridkations [TaN] + mit Methan ist mittels FT‐ICR‐Massenspektrometrie und genauen quantenchemischen Rechnungen untersucht worden. Durch diesen experimentell‐theoretischen Ansatz konnten mechanistische Details einer hocheffizienten C‐N‐Kupplung aufgeklärt werden. Im Unterschied zu [TaN] + sind die leichteren Nitride [VN] + und [NbN] + unter thermischen Bedingungen gegenüber Methan inert. Die Ursachen dieser deutlich unterschiedlichen Effizienzen der drei Nitride konnten durch CCSD(T)‐Rechnungen aufgeklärt werden." @default.
- W2511755013 created "2016-09-16" @default.
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- W2511755013 date "2016-08-11" @default.
- W2511755013 modified "2023-09-30" @default.
- W2511755013 title "Effiziente, thermische Aktivierung von Methan durch TaN<sup>+</sup> unter C-N-Kupplung" @default.
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- W2511755013 doi "https://doi.org/10.1002/ange.201606259" @default.
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