Matches in SemOpenAlex for { <https://semopenalex.org/work/W2511860110> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2511860110 endingPage "8504" @default.
- W2511860110 startingPage "8498" @default.
- W2511860110 abstract "The reaction of NH3 with •OH or SO4•- radicals produces the aminyl radical, •NH2. Pulse radiolysis and laser flash photolysis techniques were utilized to study the formation of this radical, its absorption spectrum, its reaction with O2, and the mechanism of formation of subsequent intermediates and the main final product, peroxynitrite. The rates of formation of •NH2 and its absorption spectrum are in agreement with previous reports. The reaction of •NH2 with O2, however, was observed to take place much more rapidly than reported before and to involve an equilibrium of these reactants with the aminylperoxyl radical, NH2O2•. The equilibrium is shifted toward completion of the reaction via catalyzed decomposition of this peroxyl radical, and this decomposition affects the observed rate of reaction of •NH2 with O2. The peroxyl radical deprotonates and isomerizes and finally forms NO. In the presence of O2•-, NO is converted rapidly to peroxynitrite, ONO2-. This product, which is stable at alkaline pH, was c..." @default.
- W2511860110 created "2016-09-16" @default.
- W2511860110 creator A5024591905 @default.
- W2511860110 creator A5026110103 @default.
- W2511860110 creator A5064613304 @default.
- W2511860110 creator A5086270048 @default.
- W2511860110 date "1998-07-15" @default.
- W2511860110 modified "2023-10-13" @default.
- W2511860110 title "Kinetics and Mechanism of the Reaction of <sup>•</sup>NH<sub>2</sub> with O<sub>2</sub> in Aqueous Solutions" @default.
- W2511860110 cites W140901934 @default.
- W2511860110 cites W1965621655 @default.
- W2511860110 cites W1974355116 @default.
- W2511860110 cites W1976479057 @default.
- W2511860110 cites W1981567239 @default.
- W2511860110 cites W1999361151 @default.
- W2511860110 cites W2009338549 @default.
- W2511860110 cites W2012634726 @default.
- W2511860110 cites W2020352841 @default.
- W2511860110 cites W202962716 @default.
- W2511860110 cites W2033997308 @default.
- W2511860110 cites W2066875976 @default.
- W2511860110 cites W2084100047 @default.
- W2511860110 cites W2091177995 @default.
- W2511860110 cites W2109893157 @default.
- W2511860110 cites W2134960252 @default.
- W2511860110 cites W2161930827 @default.
- W2511860110 cites W2504938558 @default.
- W2511860110 cites W271501260 @default.
- W2511860110 cites W3083311034 @default.
- W2511860110 cites W314323317 @default.
- W2511860110 cites W4231966714 @default.
- W2511860110 doi "https://doi.org/10.1021/jp981529+" @default.
- W2511860110 hasPublicationYear "1998" @default.
- W2511860110 type Work @default.
- W2511860110 sameAs 2511860110 @default.
- W2511860110 citedByCount "47" @default.
- W2511860110 countsByYear W25118601102012 @default.
- W2511860110 countsByYear W25118601102013 @default.
- W2511860110 countsByYear W25118601102016 @default.
- W2511860110 countsByYear W25118601102018 @default.
- W2511860110 countsByYear W25118601102019 @default.
- W2511860110 countsByYear W25118601102020 @default.
- W2511860110 countsByYear W25118601102021 @default.
- W2511860110 countsByYear W25118601102022 @default.
- W2511860110 countsByYear W25118601102023 @default.
- W2511860110 crossrefType "journal-article" @default.
- W2511860110 hasAuthorship W2511860110A5024591905 @default.
- W2511860110 hasAuthorship W2511860110A5026110103 @default.
- W2511860110 hasAuthorship W2511860110A5064613304 @default.
- W2511860110 hasAuthorship W2511860110A5086270048 @default.
- W2511860110 hasConcept C121332964 @default.
- W2511860110 hasConcept C147597530 @default.
- W2511860110 hasConcept C147789679 @default.
- W2511860110 hasConcept C148898269 @default.
- W2511860110 hasConcept C161790260 @default.
- W2511860110 hasConcept C178790620 @default.
- W2511860110 hasConcept C184651966 @default.
- W2511860110 hasConcept C185592680 @default.
- W2511860110 hasConcept C2993277463 @default.
- W2511860110 hasConcept C36663273 @default.
- W2511860110 hasConcept C62520636 @default.
- W2511860110 hasConcept C65024703 @default.
- W2511860110 hasConcept C89611455 @default.
- W2511860110 hasConceptScore W2511860110C121332964 @default.
- W2511860110 hasConceptScore W2511860110C147597530 @default.
- W2511860110 hasConceptScore W2511860110C147789679 @default.
- W2511860110 hasConceptScore W2511860110C148898269 @default.
- W2511860110 hasConceptScore W2511860110C161790260 @default.
- W2511860110 hasConceptScore W2511860110C178790620 @default.
- W2511860110 hasConceptScore W2511860110C184651966 @default.
- W2511860110 hasConceptScore W2511860110C185592680 @default.
- W2511860110 hasConceptScore W2511860110C2993277463 @default.
- W2511860110 hasConceptScore W2511860110C36663273 @default.
- W2511860110 hasConceptScore W2511860110C62520636 @default.
- W2511860110 hasConceptScore W2511860110C65024703 @default.
- W2511860110 hasConceptScore W2511860110C89611455 @default.
- W2511860110 hasIssue "44" @default.
- W2511860110 hasLocation W25118601101 @default.
- W2511860110 hasOpenAccess W2511860110 @default.
- W2511860110 hasPrimaryLocation W25118601101 @default.
- W2511860110 hasRelatedWork W1680813681 @default.
- W2511860110 hasRelatedWork W1846917069 @default.
- W2511860110 hasRelatedWork W2019594594 @default.
- W2511860110 hasRelatedWork W2057849849 @default.
- W2511860110 hasRelatedWork W2364614865 @default.
- W2511860110 hasRelatedWork W2369058408 @default.
- W2511860110 hasRelatedWork W3158316286 @default.
- W2511860110 hasRelatedWork W328453795 @default.
- W2511860110 hasRelatedWork W4250341545 @default.
- W2511860110 hasRelatedWork W4386804690 @default.
- W2511860110 hasVolume "102" @default.
- W2511860110 isParatext "false" @default.
- W2511860110 isRetracted "false" @default.
- W2511860110 magId "2511860110" @default.
- W2511860110 workType "article" @default.