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- W2512340841 abstract "The theory of catalytic nano-impacts is developed specifically for the case of a single particle in contact with an electrode for a short period of time in which it mediates electron transfer to or from a species in homogeneous solution. The theory is applied to impacts of chemically modified graphene nanoplatelets in which the immobilized ferrocene/ferrocenium couple is used to mediate the oxidation of l-cysteine in aqueous solution. Theory and experiment are in good agreement, and the catalytic rate constant is found to be (2.4 ± 1.2) × 103 M–1 s–1." @default.
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- W2512340841 date "2016-08-31" @default.
- W2512340841 modified "2023-10-06" @default.
- W2512340841 title "Catalytic Single-Particle Nano-Impacts: Theory and Experiment. Poly(vinylferrocene)-Modified Graphene Nanoplatelet Mediated l-Cysteine Oxidation" @default.
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- W2512340841 doi "https://doi.org/10.1021/acs.jpcc.6b07357" @default.
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