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- W2512355312 abstract "A ligand-controlled regiodivergent and stereospecific copper-catalyzed alkylboration of unactivated terminal alkynes has been developed. Anti-Markovnikov alkylboration products were obtained with dppbz as ligand; conversely, Markovnikov alkylboration products were obtained with DMAP as ligand. This reaction not only presents a direct route to construct a vinyl C(sp2)–C(sp3) bond but also provides an efficient way to synthesize both internal and external vinylboronic esters regiodivergently from a single unactivated terminal alkyne." @default.
- W2512355312 created "2016-09-16" @default.
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- W2512355312 date "2016-08-30" @default.
- W2512355312 modified "2023-10-14" @default.
- W2512355312 title "Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Unactivated Terminal Alkynes" @default.
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- W2512355312 doi "https://doi.org/10.1021/acscatal.6b02039" @default.
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