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- W2512416117 abstract "Abstract The development of robust membranes able to withstand harsh environments such as oxidative conditions would improve the sustainability of several separation processes. Therefore, organosilica and ceramic non-commercial membranes were characterized and their performances were compared before and after contact with hydrogen peroxide. The organosilica membrane showed a high level of solute rejection coefficients (0.928 for NaCl and 0.969 for MgCl 2 ), but low permeability (5.04·10 –13 m 3 /m 2 s Pa, equivalent to 0.181 L/m 2 h bar). The ceramic membrane, however, showed low solute rejection (0.187 for NaCl and 0.649 for MgSO 4 ), but high membrane permeability (7.05·10 –12 m 3 /m 2 s Pa, equivalent to 2.538 L/m 2 h bar). While the organosilica membrane was quite sensitive to the presence of hydrogen peroxide, the chemical stability of the ceramic membrane in 30% hydrogen peroxide solution was very satisfactory. A Kedem-Katchalsky membrane transport model and a logistic decay model were applied to successfully test the performance of the membranes and to characterize the evolution of the organosilica membrane, respectively." @default.
- W2512416117 created "2016-09-16" @default.
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- W2512416117 date "2016-12-01" @default.
- W2512416117 modified "2023-10-17" @default.
- W2512416117 title "Evaluation of non-commercial ceramic SiO2-ZrO2 and organosilica BTESE membranes in a highly oxidative medium: Performance in hydrogen peroxide" @default.
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- W2512416117 doi "https://doi.org/10.1016/j.memsci.2016.08.042" @default.
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