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- W2512464513 abstract "Nanohybrids of zinc selenide and smectites (a natural montmorillonite and a synthetic saponite) were prepared by a hydrothermal reaction of zinc chloride and sodium selenosulfite in the presence of smectites. The products were characterized by powder X-ray diffraction, scanning and transmission electron microscopies, thermogravimetric analysis, as well as, UV–visible and photoluminescence spectroscopies. The round-shaped zinc selenide nanoparticles with the average diameter of 1–4 nm formed in the interlayer space of smectites, which gave the absorption onsets at 379–456 nm for montmorillonite system and at 475 nm for saponite system. Additional absorption onsets were observed at around 478–665 nm for montmorillonite system and at 609–682 nm for saponite system, suggesting the larger-sized particles formed at the external surfaces. The photoluminescence observed in the wavelength range of 357–360 nm was interpreted to the formation of zinc selenide nanoparticles in smectites. The increase of the photoluminescence intensities of all the products (from 35 for bulk ZnSe to 126–294 for ZnSe(n)-smectites) was thought to be caused by the interactions with smectites and/or size and shape of ZnSe formed in the hybrids." @default.
- W2512464513 created "2016-09-16" @default.
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- W2512464513 date "2017-01-01" @default.
- W2512464513 modified "2023-10-17" @default.
- W2512464513 title "Hydrothermal synthesis of zinc selenide in smectites" @default.
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- W2512464513 doi "https://doi.org/10.1016/j.clay.2016.09.002" @default.
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