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- W2512633818 abstract "I.R. studies of adsorbed water and alkylbenzenes on BeO or Ni-BeO were carried out, and the results were used to explain the previously reported activity data. The experimental results showed that both BeO-A which has a number of micro-pores and BeO-B which has little micro-pores showed such I.R. spectra as indicated that the adsorbed water forms an active hydroxy-group which readily reacts with D2O vapor to form a deuterio-hydroxy-group. Further, both Ni-BeO-A (an active and selective catalyst) and Ni-BeO-B (an inactive and inselective catalyst) gave spectra which suggest a strong adsorption of alkylbenzene on the surface of metallic nickel contained in the catalysts. In contrast with the above-mentioned I.R. data, only BeO-A which has a number of micro-pores gave I.R. spectra of the adsorbed alkylbenzenes. Comparisons of these I.R. data with the previously reported kinetic model of the alkylbenzene-steam reaction and the structural models of the Ni-BeO-A and Ni-BeO-B gave reasonable explanations on the catalytic properties of these catalysts." @default.
- W2512633818 created "2016-09-16" @default.
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- W2512633818 date "1975-01-01" @default.
- W2512633818 modified "2023-09-23" @default.
- W2512633818 title "Infrared Spectra of Adsorbed Water and Alkylbenzenes on BeO or Ni-BeO and the Catalytic Properties of Some Typical Ni-BeO Systems" @default.
- W2512633818 cites W410805017 @default.
- W2512633818 doi "https://doi.org/10.1627/jpi1958.18.102" @default.
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