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- W2512897570 abstract "High glum values of +0.30 (ΔJ = 1, 591 nm, in DMSO) and -0.23 (ΔJ = 1, 589 nm, in H2O) were recorded in our series of newly designed macrocyclic europium(III) complexes. A sterically locking approach involving a bidentate chromophore is adopted to control the formation of one stereoisomer, giving rise to extreme rigidity, high stability, and high emission intensity. The combination of a chiral substituent on a macrocyclic chelate for lanthanide ions opens up new perspectives for the further development of circulary polarized luminescent chiral tags in optical and bioapplications." @default.
- W2512897570 created "2016-09-16" @default.
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- W2512897570 date "2016-08-18" @default.
- W2512897570 modified "2023-10-18" @default.
- W2512897570 title "New Class of Bright and Highly Stable Chiral Cyclen Europium Complexes for Circularly Polarized Luminescence Applications" @default.
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- W2512897570 doi "https://doi.org/10.1021/acs.inorgchem.6b01546" @default.
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