FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2513105280> ?p ?o ?g. }

• W2513105280 endingPage "627" @default.
• W2513105280 startingPage "621" @default.
• W2513105280 abstract "To reveal the antifreeze protection mechanism of an aqueous solution of ethylene glycol (EG) at a molecular level, concentration-dependent infrared spectra are analyzed with an aid of chemometrics. The principal component analysis (PCA) of the spectra reveals that the spectral variation is explained by the quantity changes not only of ‘bulky water’ and the ‘bulky EG,’ but also of a ‘water/EG complex.’ After a spectral decomposition using the alternative least squares (ALS) analysis, the spectrum of the complex reveals that the EG molecule keeps the gauche conformation, and the terminal hydroxyl groups are hydrogen bonded by water molecules, which is a key to understand the antifreeze effect. In addition, the complex is found to comprises an EG molecule with four water molecules. Since the quantity of the complex attains the maximum at an EG concentration of 60 wt%, at which the freezing point becomes lowest, the complex is concluded to be a key hydrated species for the antifreeze effect. The generation process of the water/EG complex is also studied by using the time-resolved IR spectroscopy, which consistently confirms the spectral discussion made above." @default.
• W2513105280 created "2016-09-16" @default.
• W2513105280 creator A5051127358 @default.
• W2513105280 creator A5070475062 @default.
• W2513105280 date "2016-11-01" @default.
• W2513105280 modified "2023-10-10" @default.
• W2513105280 title "Molecular structural analysis of hydrated ethylene glycol accounting for the antifreeze effect by using infrared attenuated total reflection spectroscopy" @default.
• W2513105280 cites W1560168292 @default.
• W2513105280 cites W1603607478 @default.
• W2513105280 cites W1964490855 @default.
• W2513105280 cites W1986585987 @default.
• W2513105280 cites W1991172614 @default.
• W2513105280 cites W2003003096 @default.
• W2513105280 cites W2003501903 @default.
• W2513105280 cites W2011092339 @default.
• W2513105280 cites W2019438192 @default.
• W2513105280 cites W2023444704 @default.
• W2513105280 cites W2030258141 @default.
• W2513105280 cites W2039326581 @default.
• W2513105280 cites W2044921728 @default.
• W2513105280 cites W2062944657 @default.
• W2513105280 cites W2071363458 @default.
• W2513105280 cites W2088346024 @default.
• W2513105280 cites W2126619155 @default.
• W2513105280 cites W2148265049 @default.
• W2513105280 cites W2316747396 @default.
• W2513105280 cites W2322289652 @default.
• W2513105280 doi "https://doi.org/10.1016/j.molliq.2016.08.097" @default.
• W2513105280 hasPublicationYear "2016" @default.
• W2513105280 type Work @default.
• W2513105280 sameAs 2513105280 @default.
• W2513105280 citedByCount "20" @default.
• W2513105280 countsByYear W25131052802017 @default.
• W2513105280 countsByYear W25131052802018 @default.
• W2513105280 countsByYear W25131052802019 @default.
• W2513105280 countsByYear W25131052802020 @default.
• W2513105280 countsByYear W25131052802021 @default.
• W2513105280 countsByYear W25131052802022 @default.
• W2513105280 countsByYear W25131052802023 @default.
• W2513105280 crossrefType "journal-article" @default.
• W2513105280 hasAuthorship W2513105280A5051127358 @default.
• W2513105280 hasAuthorship W2513105280A5070475062 @default.
• W2513105280 hasBestOaLocation W25131052802 @default.
• W2513105280 hasConcept C113196181 @default.
• W2513105280 hasConcept C120665830 @default.
• W2513105280 hasConcept C121332964 @default.
• W2513105280 hasConcept C141734981 @default.
• W2513105280 hasConcept C147789679 @default.
• W2513105280 hasConcept C151304367 @default.
• W2513105280 hasConcept C153642686 @default.
• W2513105280 hasConcept C158355884 @default.
• W2513105280 hasConcept C178790620 @default.
• W2513105280 hasConcept C184651966 @default.
• W2513105280 hasConcept C185592680 @default.
• W2513105280 hasConcept C2776170207 @default.
• W2513105280 hasConcept C2777516009 @default.
• W2513105280 hasConcept C2992111332 @default.
• W2513105280 hasConcept C32891209 @default.
• W2513105280 hasConcept C32909587 @default.
• W2513105280 hasConcept C43617362 @default.
• W2513105280 hasConcept C49102809 @default.
• W2513105280 hasConcept C55493867 @default.
• W2513105280 hasConcept C62520636 @default.
• W2513105280 hasConcept C97355855 @default.
• W2513105280 hasConceptScore W2513105280C113196181 @default.
• W2513105280 hasConceptScore W2513105280C120665830 @default.
• W2513105280 hasConceptScore W2513105280C121332964 @default.
• W2513105280 hasConceptScore W2513105280C141734981 @default.
• W2513105280 hasConceptScore W2513105280C147789679 @default.
• W2513105280 hasConceptScore W2513105280C151304367 @default.
• W2513105280 hasConceptScore W2513105280C153642686 @default.
• W2513105280 hasConceptScore W2513105280C158355884 @default.
• W2513105280 hasConceptScore W2513105280C178790620 @default.
• W2513105280 hasConceptScore W2513105280C184651966 @default.
• W2513105280 hasConceptScore W2513105280C185592680 @default.
• W2513105280 hasConceptScore W2513105280C2776170207 @default.
• W2513105280 hasConceptScore W2513105280C2777516009 @default.
• W2513105280 hasConceptScore W2513105280C2992111332 @default.
• W2513105280 hasConceptScore W2513105280C32891209 @default.
• W2513105280 hasConceptScore W2513105280C32909587 @default.
• W2513105280 hasConceptScore W2513105280C43617362 @default.
• W2513105280 hasConceptScore W2513105280C49102809 @default.
• W2513105280 hasConceptScore W2513105280C55493867 @default.
• W2513105280 hasConceptScore W2513105280C62520636 @default.
• W2513105280 hasConceptScore W2513105280C97355855 @default.
• W2513105280 hasFunder F4320320912 @default.
• W2513105280 hasFunder F4320334764 @default.
• W2513105280 hasLocation W25131052801 @default.
• W2513105280 hasLocation W25131052802 @default.
• W2513105280 hasOpenAccess W2513105280 @default.
• W2513105280 hasPrimaryLocation W25131052801 @default.
• W2513105280 hasRelatedWork W1166426461 @default.
• W2513105280 hasRelatedWork W1994643710 @default.
• W2513105280 hasRelatedWork W2001433076 @default.
• W2513105280 hasRelatedWork W2077656758 @default.
• W2513105280 hasRelatedWork W2085756095 @default.
• W2513105280 hasRelatedWork W2349932406 @default.
• W2513105280 hasRelatedWork W2370305094 @default.

• next