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• W2513259458 abstract "Acrylonitrile (AN)-containing copolymers have not been widely considered as barrier dispersed phases in blends with poly(ethylene) (PE), despite the versatility in their synthesis (i.e. controlled radical radical polymerization). To use such copolymers in PE, compatibilization is essential to obtain the desired morphology and thus we made a primary amine functional monomer, IDBA (3-isopropenyl-α,α–dimethylbenzylamine), with minimal purification steps, high yield (up to 76%) and high conversion (98%) in multi-gram batches from a cheap, commercially available precursor m-TMI (3-isopropenylα,α−dimethylbenzyl isocyanate). Terpolymers of AN, IDBA, MA (methyl acrylate) and AN (acrylonitrile) were then synthesized in DMF solution by conventional radical polymerization (number average molecular weight" @default.
• W2513259458 created "2016-09-16" @default.
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• W2513259458 date "2016-01-01" @default.
• W2513259458 modified "2023-10-03" @default.
• W2513259458 title "Synthesis of Pendant Amine Functional Methyl Acrylate/Acrylonitrile Copolymers and Reactively Compatibilized Blends with Poly(Ethylene)" @default.
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• W2513259458 doi "https://doi.org/10.14355/papt.2016.04.007" @default.
• W2513259458 hasPublicationYear "2016" @default.
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