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- W2513421926 endingPage "8603" @default.
- W2513421926 startingPage "8595" @default.
- W2513421926 abstract "A convenient and general synthesis of 2-thiocarbohydrates via cerium ammonium nitrate oxidation of the thiocyanate ion is described. Radical addition to glycals proceeds with excellent regio- and good stereoselectivities in only one step, deprotection affords water-soluble 2-thio saccharides. Binding studies to Con A have been performed by isothermal titration calorimetry (ITC) and saturation transfer difference (STD) NMR spectroscopy. The 2-thiomannose derivative binds even stronger to Con A than the natural substrate, offering opportunities for new lectin or enzyme inhibitors." @default.
- W2513421926 created "2016-09-16" @default.
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- W2513421926 date "2016-08-30" @default.
- W2513421926 modified "2023-09-29" @default.
- W2513421926 title "Synthesis of 2-Thiocarbohydrates and Their Binding to Concanavalin A" @default.
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- W2513421926 doi "https://doi.org/10.1021/acs.joc.6b00987" @default.
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