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- W251420061 abstract "A study was carried out on the effect of the phosphine ligand structure on the rate and regioselectivity of the hydrocarboxylation of 1-heptene in dioxane in the presence of the PdCl/sub 2/(PR/sub 3/)/sub 2/-PR/sub 3/ catalytic system (R = aryl, alkyl). An increase in the basicity of phosphines with similar conic angle values leads to a decrease in the reaction rate and increase in selectivity. An increase in the conic angle in phosphines with similar pK/sub a/ values leads to a decrease in the selectivity relative to formation of the linear isomer." @default.
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- W251420061 date "1986-06-20" @default.
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- W251420061 title "Effect of phosphine ligands on the activity and selectivity of Pd(II) complexes in the catalysis of the hydrocarboxylation of olefins" @default.
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