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- W2514403431 abstract "The surface dynamics of polyhedral oligomeric silsesquioxane (POSS)-functionalized polystyrene (PS-POSS) thin films above the glass transition temperature were studied by grazing-incidence X-ray photon correlation spectroscopy in order to elucidate the effects of POSS at the end of the polystyrene chains. Much slower fluctuations were observed in the surface of PS-POSS thin films than in the polystyrene thin films, despite the negligible difference in their bulk viscosity. Quantitative analysis based on fluctuation-dissipation theorem indicated that there is a high-viscosity layer at the surface of the PS-POSS films, and that the substrate interface originated from POSS segregation." @default.
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- W2514403431 date "2016-11-01" @default.
- W2514403431 modified "2023-10-09" @default.
- W2514403431 title "Observation of constraint surface dynamics of polystyrene thin films by functionalization of a silsesquioxane cage" @default.
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- W2514403431 doi "https://doi.org/10.1016/j.polymer.2016.08.040" @default.
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